STRUCTURE OF BIS(TETRAETHYLAMMONIUM)BIS[BIS(PHENYLTHIOLATO) (μ-SULFIDO)-IRON(Ⅲ)],(Et4N)2[Fe2S2(SC6H5)4]

被引：0

作者：

Cai Jinhua Cheng ChangnengFujian Institute of Research on the Structure of Matter

Acadewia Sinica

机构：

来源：

结构化学 | 1985年 / 03期

关键词：

Fe; PHENYLTHIOLATO; SULFIDO; Et4N)2[Fe2S2; IRON; TETRAETHYLAMMONIUM)BIS[BIS; SC6H5)4;

D O I：

10.14102/j.cnki.0254-5861.1985.03.008

中图分类号：

学科分类号：

摘要：

<正> Mr= 873.02, orthorhombic P21212, a= 16.153(3), b= 15.718(2), c= 8.847(3) A, V= 2246.2(14)A3, Z=2, Dx? 1.291gcm-3, MoK(?), radiation, λ= 0.71069A, μ= 9.417mm-1, F(000)= 924, R(Rw)= 0.073(0.069) for 1936 observed reflections. The structure of the anion contains a FesSz core, in which each iron atom is coordinated by two μ2-S atoms and two thiolate sulfur atoms to form a distorted tetrahedron.

引用

页码：199 / 202

页数：4