Excellent reusability of FeBC amorphous ribbons induced by progressive formation of through-pore structure during acid orange 7 degradation

被引:9
作者
Fang Miao [1 ]
Qianqian Wang [1 ]
Qiaoshi Zeng [1 ]
Long Hou [1 ]
Tao Liang [1 ]
Zhiqiang Cui [1 ]
Baolong Shen [1 ,2 ]
机构
[1] School of Materials Science and Engineering, Jiangsu Key Laboratory for Advanced Metallic Materials, Southeast University
[2] Institute of Massive Amorphous Metal Science, China University of Mining and Technology
关键词
3D nanosheet arrays; Through-pore; Wastewater treatment; FeBC amorphous alloys; Synchrotron XRD;
D O I
暂无
中图分类号
TB383.1 []; X703 [废水的处理与利用];
学科分类号
070205 ; 080501 ; 1406 ; 083002 ;
摘要
The high-efficient degrading ability of Fe BC amorphous ribbons toward acid orange 7(AO7) via redox reactions is reported and compared with that of Fe PC amorphous ribbons. The time required for degrading50% of AO7 using Fe BC amorphous ribbons is only 1/3 of that using Fe PC amorphous ribbons. In the Fe BC amorphous matrix, galvanic cell structures are formed between the Fe-B and Fe-C bonds because of the large difference in their bonding strengths, which contributes to the low reaction activation energy and the high degrading efficiency of Fe BC amorphous ribbons. The extremely long service life of Fe BC amorphous ribbons comes from the progressive formation of 3 D porous nanosheet networks that allow more efficient mass transport and a larger specific surface area. The Fe BC amorphous ribbons show a satisfying degrading ability in not only acidic but also neutral and weak alkaline AO7 solutions. This work provides an effective and environmental-friendly material for degrading azo dyes.
引用
收藏
页码:107 / 118
页数:12
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