Synthesis,Crystal Structure and Antimicrobial Study of N,N,N'-Tris(3-aminopropyl)ethylenediamine Copper(Ⅱ) Diperchlorate

被引：0

作者：

许兴友 ^{[1
]}

许同桃 ^{[2
]}

高健 ^{[3
]}

王大奇 ^{[4
]}

陆路德 ^{[2
]}

徐国想 ^{[1
]}

机构：

[1] Key Marine Biotechnology Laboratary,Huaihai Institute of Technology

[2] Materials Chemistry Laboratory,Nanjing University of Science&Technology

[3] Department of Chemical Engineering,Lianyungang Technical College

[4] College of Chemistry and Chemical Engineering,Liaocheng University

来源：

Chinese Journal of Structural Chemistry | 2007年 / 01期

关键词：

N; N-tris(3-aminopropyl)ethylenediamine; copper compound; crystal structure; antimicrobial activity;

D O I：

10.14102/j.cnki.0254-5861.2007.01.022

中图分类号：

O621.25 [];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound [Cu(C11H29N5)](ClO4)2 was synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The compound crystallizes in the monoclinic system, space group P21/n with a = 9.405(2), b = 14.495(3), c = 14.715(3) , β = 90.262(3)°, V = 2006.1(7) 3, Mr = 493.83, Z = 4, F(000) = 1028, Dc = 1.635 g/cm3, T = 298(2) K, μ = 1.403 mm-1 and λ = 0.71073 . The structure was refined to R = 0.0508 and wR = 0.1250 for 2293 observed reflections with I > 2σ(I). The Cu(Ⅱ) atom possesses a five-coordinate CuN5 environment which shows a slightly distorted square-pyramidal geometry. Antimicrobial activity study found that the complex is active against Salmonella species, Staphylococcus aureu, Bacillus pumilus and Bacillus coliforms.

引用

页码：121 / 125

页数：5