Theoretical Studies on the Third-order Nonlinear Optical Properties and Two-photon Absorption of Stilbene Derivatives

被引：0
作者：
任爱民
封继康
刘孝娟
机构：
[1] State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry , Jilin University, Changchun, Jilin 130023, China,State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry , Jil
[2] College of Chemistry, Jilin University, Changchun, Jilin 130023, China ,State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry , Jilin University, Changchun, Jilin 130023, China
来源：
ChineseJournalofChemistry | 2004年 / 03期
基金：
中国国家自然科学基金;
关键词：
stilbene derivative; electronic spectrum; two-photon absorption cross-section;
D O I：
暂无
中图分类号：
O647.3 [吸附];
学科分类号：
070304 ; 081704 ;
摘要：
Different types of stilbene derivatives (D-p-D, A-p-A, D-p-A) were investigated with AM1, and specially, equilibrium geometries of symmetrical stilbene derivatives (D-p-D) were studied using of PM3. With the same method INDO/CI, the UV-vis spectra were explored and the position and strength of the two-photon absorption were predicated by Sum-Over-States expression. The relationships of the structures, spectra and nonlinear optical properties have been examined. The influence of various substituents on two photon absorption cross-sections was discussed micromechanically.
引用
收藏
页码：243 / 251 +220
页数：10
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