Vibrational effects on electron momentum distributions of outer valence orbitals of benzene

被引:0
作者
张钰 [1 ]
牛珊珊 [1 ]
唐亚国 [1 ]
王忆纯 [1 ]
单旭 [1 ]
陈向军 [1 ]
机构
[1] Hefei National Laboratory for Physical Sciences at the Microscale and Department of Modern Physics,University of Science and Technology of China
关键词
electron momentum spectroscopy; benzene; outer valence orbitals; vibrational effects;
D O I
暂无
中图分类号
O625.11 [单环烃(苯系烃)];
学科分类号
070303 ; 081704 ;
摘要
The outer valence electron momentum distributions of benzene are reinvestigated with theoretical calculations involving the vibrational effects.The results are compared with recent experimental measurements [Phys.Rev.A 98 042705(2018)].The significant discrepancies between theories and experiments in previous works have now been interpreted quantitatively,indicating that the vibrational motion in benzene molecule has noticeable influence on its electron momentum distributions.
引用
收藏
页码:312 / 317
页数:6
相关论文
共 49 条
  • [21] Investigation of outer valence orbital of CF2Cl2 by a new type of electron momentum spectrometer
    Ning, CG
    Ren, XG
    Deng, JK
    Su, GL
    Zhang, SF
    Huang, F
    Li, GQ
    CHINESE PHYSICS, 2005, 14 (12): : 2467 - 2473
  • [22] Electron Momentum Spectroscopy Investigation of Molecular Conformations of Ethanol Considering Vibrational Effects
    Tang, Yaguo
    Shan, Xu
    Niu, Shanshan
    Liu, Zhaohui
    Wang, Enliang
    Watanabe, Noboru
    Yamazaki, Masakazu
    Takahashi, Masahiko
    Chen, Xiangjun
    JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 121 (01) : 277 - 287
  • [23] Electron momentum spectroscopy study on inner orbitals of methyl iodide
    Zhao, Min-fu
    Niu, Shan-shan
    Tian, Qi-guo
    Yang, Jing
    Shan, Xu
    Chen, Xiang-jun
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2021, 34 (03) : 281 - 286
  • [24] Electron Momentum Spectroscopy of Valence Orbitals of n-Propyl Iodide: Spin-Orbit Coupling Effect and Intramolecular Orbital Interaction
    Wang, En-liang
    Shi, Yu-feng
    Shan, Xu
    Yang, Hong-jiang
    Zhang, Wei
    Chen, Xiang-jun
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2014, 27 (05) : 503 - 511
  • [25] Electron Momentum Spectroscopy of Ethanethiol Complete Valence Shell
    Xue, Xin-xia
    Yan, Mi
    Wu, Fang
    Shan, Xu
    Xu, Ke-zun
    Chen, Xiang-jun
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2008, 21 (06) : 515 - 520
  • [26] Experimental and theoretical study of the valence electronic structure of propane by electron momentum spectroscopy
    Niu, Shanshan
    Tang, Yaguo
    Liu, Zhaohui
    Shan, Xu
    Chen, Xiangjun
    JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2018, 229 : 52 - 60
  • [27] An investigation of the two outermost orbitals of glyoxal and biacetyl by electron momentum spectroscopy
    Takahashi, M
    Saito, T
    Udagawa, Y
    ELECTRON SCATTERING: FROM ATOMS, MOLECULES, NUCLEI, AND BULK MATTER, 2005, : 265 - 278
  • [28] Assessment of delocalized and localized molecular orbitals through electron momentum spectroscopy
    Liu Yuan
    Cheung Ling-Fung
    Ning Chuan-Gang
    CHINESE PHYSICS B, 2014, 23 (06)
  • [29] High Resolution Electron Momentum Spectroscopy Study on Ethanol: Orbital Electron Momentum Distributions for Individual Conformers
    Li, Meng
    Shan, Xu
    Niu, Shan-shan
    Tang, Ya-guo
    Wu, Fang
    Xu, Chun-kai
    Chen, Xiang-jun
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2016, 29 (06) : 645 - 649
  • [30] Electron momentum spectroscopy of the frontier molecular orbitals of CF2BrCl
    Shan, X
    Chen, LQ
    Chen, XJ
    Yang, XF
    Li, ZJ
    Liu, T
    Zheng, YY
    Xu, KZ
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2005, 18 (03) : 295 - 297