Overview of acidic deep eutectic solvents on synthesis, properties and applications

被引：11

作者：

Hao Qin ^{[1
]}

Xutao Hu ^{[1
]}

Jingwen Wang ^{[1
]}

Hongye Cheng ^{[1
]}

Lifang Chen ^{[1
]}

Zhiwen Qi ^{[1
]}

机构：

[1] Max Planck Partner Group at the State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology

来源：

GreenEnergy&Environment | 2020年 / 5卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Acidic deep eutectic solvent; Br?nsted acidity; Lewis acidity; Green chemistry;

D O I：

暂无

中图分类号：

TQ413 [溶剂];

学科分类号：

0817 ;

摘要：

This review divides the acidic deep eutectic solvents(ADES) into Br?nsted and Lewis DES according to their diversity of acidic character.The hydrogen bond donors and halide salts for formulating an ADES are classified, the synthesis methods are described, and the physicochemical properties including freezing point, acidity, density, viscosity and conductivity are presented. Furthermore, the applications of Br?nsted acidic deep eutectic solvents(BADES) and Lewis acidic deep eutectic solvents(LADES) are overviewed, respectively, covering the fields in dissolution, extraction, organic reaction and metal electrodeposition. It is expected that the ADES has great potential to replace the pollutional mineral acid, expensive and unstable solid acid, and costly ionic liquid in many acid-employed chemical processes, thus meeting the demands of green chemistry.

引用

页码：8 / 21

页数：14