Crystal Structures of Co(Ⅱ) and Cu(Ⅱ) Complexes and Ammonium Salt Involving Ethylenediamine

被引：1

作者：

LUO Mei ^{[1
]}

WANG Lei ^{[1
]}

QIU Jing-Jing ^{[1
]}

ZHANG Jia-Hai ^{[2
]}

LI Qian-Rong ^{[2
]}

YIN Hao ^{[2
]}

机构：

[1] Hefei University of Technology,Department of Chemical Engineering

[2] University of Science and Technology of China

来源：

结构化学 | 2013年 / 32卷 / 12期

关键词：

Co(II) complex I; ammonium salt II; 2-ethylenediamine; cobaltous acetate tetrahydrate; manganese acetate tetrahydrate; N; N-bis(salicylidene)ethylenediamine; Cu(OAc)2 ·H2 O;

D O I：

10.14102/j.cnki.0254-5861.2013.12.008

中图分类号：

O627.8 [第Ⅷ族元素有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

The Co(II)complex I and ammonium salt II were synthesized from the direct reaction of 1,2-ethylenediamine and cobaltous acetate tetrahydrate and manganese acetate tetrahydrate in anhydrous ethanol.Treatment of N,N-bis(salicylidene)ethylenediamine with Cu(OAc)2·H2O results in the formation of Cu(II)complex III.C14H37CoN4O8(I):triclinic,space group P1,a=8.6296(12),b=12.0291(17),c=12.1108(17),α=75.335(2),β=69.991(2),γ=72.248(2)o,V=1109.4(3)3,Z=2,ρcalcd=1.342 g/cm3,the final R=0.0342 for 4817 observed reflections with I>2(I)and Rw=0.1263 for all data.C6H16N2O4(II):space group P1,a=5.5513(10),b=5.5589(11),c=7.4437(14),α=94.332(4),β=104.497(4),γ=103.487(4)o,V=214.06(7)3,Z=1,ρcalcd=1.398 g/cm3,the final R=0.0431 for 829 observed reflections with I>2(I)and Rw=0.1263 for all data.C14H37CuN4O(III),space group P21/n,a=9.050(9),b=18.434(17),c=11.659(11),β=107.134(19)o,V=1859(3)3,Z=4,ρcalcd=1.443 g/cm3,the final R=0.0616 for 3308 observed reflections(I>2(I))and Rw=0.1229 for all data.Their structures were all determined by X-ray diffraction,elemental analysis and IR.

引用

页码：1835 / 1840

页数：6

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[2]

Synthesis, characterization of a novel anilido-iminato cobalt (II) complex and its application for addition polymerization of norbornene[J] . Dao Zhang,Qin Yue,Jinyang Wang,Gongwo Shigeng,Linhong Weng.Inorganic Chemistry Communications . 2009 (12)

[3]

A 3D supramolecular network of cobalt(II)(bis(4-pyridyl)ethylene) with terephthalate dianions[J] . Subal Chandra Manna,Ennio Zangrando,Joan Ribas,Nirmalendu Ray Chaudhuri.Inorganica Chimica Acta . 2007 (1)

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