SYNTHESIS AND CRYSTAL STRUCTURE OF THE Mo(O) TRINUCLEAR COMPLEXES: (Et4N)2[(CO)4Mo(μ-S)2-M(μ-S)2Mo(CO)4] (Ⅰ: M=Mo, Ⅱ: M=W)

被引:0
|
作者
萧泰
余佩华
庄伯涛
机构
[1] Northwest Normal University
[2] Fujian Institute of Research on the Structure of Matter
[3] Academia Sinica
[4] PRC
[5] Department of Chemistry
[6] Lanzhou 730070
[7] Fuzhou 350002
关键词
SYNTHESIS AND CRYSTAL STRUCTURE OF THE Mo; TRINUCLEAR COMPLEXES; M=W; Et4N; M; CO;
D O I
暂无
中图分类号
学科分类号
摘要
The complexes of lower valent molybdenum have special nature in the form of coordination and the changeability of valent state. In order to further investigate it, we synthesised the title compounds Ⅰ and Ⅱ which were trinuclear complexes containing M(O)and determined their crystal structure.
引用
收藏
页码:1669 / 1670
页数:2
相关论文
共 50 条
  • [31] CRYSTAL STRUCTURE OF MIXED-METAL CLUSTER(η5-C5H5)2Mo2Fe2(μ3-S)2(μ-CO)2(CO)6
    Cai Qingrong Zheng Bixian Huang Jinshun Lu JiaxiFuzhou Laboratory of Structural Chemistry
    结构化学, 1989, (01) : 65 - 67
  • [32] Preparation, Structures, and Some Reactivities of Five-Coordinate Alkyne Complexes of Mo with Tetraphosphine or Diphosphine Coligand [Mo(RCCR′){meso-o-C6H4(PPhCH2CH2PPh2)2}] and [Mo(RCCR′)(Ph2PCH2CH2PPh2)2]
    Niikura, Fumiya
    Seino, Hidetake
    Mizobe, Yasushi
    ORGANOMETALLICS, 2009, 28 (04) : 1112 - 1121
  • [33] Solution combustion synthesis, characterization, magnetic, and dielectric properties of CoFe2O4 and Co0.5M0.5Fe2O4 (M = Mn, Ni, and Zn)
    Bera, Parthasarathi
    Lakshmi, R., V
    Prakash, B. H.
    Tiwari, Khushubo
    Shukla, Ashish
    Kundu, Asish K.
    Biswas, Krishanu
    Barshilia, Harish C.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020, 22 (35) : 20087 - 20106
  • [34] The electronic structure, mechanical and thermodynamic properties of Mo2XB2 and MoX2B4 (X = Fe, Co, Ni) ternary borides
    Jiang, Yehua (jiangyehua@kmust.edu.cn;jfengseas.harvard.edu), 1600, American Institute of Physics Inc. (118):
  • [35] Trinuclear vanadium dialkyldithiocarbamate complexes.: Synthesis, structure and spectroscopic characterization of [Et4N][V3(μ3-S)(η2-μ-S2)3(Et2dtc)3]•2CH3CN
    Zhu, HP
    Liu, QT
    Deng, YH
    Wen, TB
    Chen, CN
    Wu, DX
    INORGANICA CHIMICA ACTA, 1999, 286 (01) : 7 - 13
  • [36] Energy Level Engineering: Ru Single Atom Anchored on Mo-MOF with a [Mo8O26(im)2]4- Structure Acts as a Biomimetic Photocatalyst
    Wang, Shuo
    Zhang, Ji-Jie
    Zong, Meng-Ya
    Xu, Jun
    Wang, Dan-Hong
    Bu, Xian-He
    ACS CATALYSIS, 2022, 12 (13) : 7960 - 7974
  • [37] M(C6X6Li6)2 (M = Cr, Mo, W; X = O, S): Transition-metal sandwich complexes with π-aromatic C6X6Li6 ligands
    Guo, Jin-Chang
    Lu, Hai-Gang
    Li, Si-Dian
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2013, 1018 : 95 - 101
  • [38] Studies on the local structures and spin Hamiltonian parameters for the rhombic Nb4+ centers in MO2 (M = Sn, Ti and Ge) crystals
    Zhang, Z. -H.
    Wu, S. -Y.
    Xu, P.
    Li, L. -L.
    Zhang, S. -X.
    EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 2011, 53 (02)
  • [39] CRYSTAL STRUCTURE OF THE MIXED-METAL CLUSTER,(η5-C5H5)2Mo2Fe2(μ4-Se)(μ3-Se)2(CO)6
    Cai Qingrong Zheng Bixian Huang Jinshun Lu JiaxiFujian Institute of Research on the Structure of Matter
    结构化学, 1987, (02) : 110 - 112
  • [40] Crystal structure and microwave dielectric properties of novel BiMg2MO6 (M = P, V) ceramics with low sintering temperature
    Zhang, Ping
    Hao, Manman
    Xiao, Mi
    Zheng, Zhentai
    JOURNAL OF MATERIOMICS, 2021, 7 (06) : 1344 - 1351