SYNTHESIS AND CRYSTAL STRUCTURE OF THE Mo(O) TRINUCLEAR COMPLEXES: (Et4N)2[(CO)4Mo(μ-S)2-M(μ-S)2Mo(CO)4] (Ⅰ: M=Mo, Ⅱ: M=W)

被引：0
|
作者：
萧泰
余佩华
庄伯涛
机构：
[1] Northwest Normal University
[2] Fujian Institute of Research on the Structure of Matter
[3] Academia Sinica
[4] PRC
[5] Department of Chemistry
[6] Lanzhou 730070
[7] Fuzhou 350002
来源：
Chinese Science Bulletin | 1992年 / 19期
关键词：
SYNTHESIS AND CRYSTAL STRUCTURE OF THE Mo; TRINUCLEAR COMPLEXES; M=W; Et4N; M; CO;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The complexes of lower valent molybdenum have special nature in the form of coordination and the changeability of valent state. In order to further investigate it, we synthesised the title compounds Ⅰ and Ⅱ which were trinuclear complexes containing M(O)and determined their crystal structure.
引用
收藏
页码：1669 / 1670
页数：2
相关论文
共 50 条
  • [21] THE CLEAVAGE REACTION OF Mo≡Mo TRIPLE BOND.SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF[CpMo（CO）2（N,S-C9H6NS）]·O=PPh3
    You Mao SHI Shi Wei Lu He Fu GUO a.Delian Institute of Chemical Physics
    ChineseChemicalLetters, 1992, (08) : 665 - 666
  • [22] Activation mechanisms of H2, O2, H2O, CO2, CO, CH4 and C2Hx on metallic Mo2C(001) as well as Mo/C terminated Mo2C(101) from density functional theory computations
    Shi, Yun
    Yang, Yong
    Li, Yong-Wang
    Jiao, Haijun
    APPLIED CATALYSIS A-GENERAL, 2016, 524 : 223 - 236
  • [23] High yield synthesis of trinuclear [M3S4X3(diphos)3]+ (M = Mo, W; X = Cl, Br and diphos = dmpe, dppe) molecular clusters from solid state materials.: Synthesis and structure of [W3S4H3(dppe)3](BPh4)
    Estevan, F
    Feliz, M
    Llusar, R
    Mata, JA
    Uriel, S
    POLYHEDRON, 2001, 20 (06) : 527 - 535
  • [24] A Novel Dodecanuclear Mo-Cu Cluster Derived from [Mo2S2(edt)2(μ-S)2]2- as a Metalloligand: Preparation and Structure of [Mo6(edt)4(μ-edt)2(μ3-S)12Cu6(μ-dppe)2]•2DMF•C6H14 (edt = -SC2H4S-)
    Li, Jing-Jing
    Duan, Taike
    Zhang, Qian-Feng
    Leung, Wa-Hung
    CHEMISTRY LETTERS, 2009, 38 (05) : 506 - 507
  • [25] The Synthesis and Crystal Structure of the First Trinuclear Molybdenum Complex Containing PyS Ligands [Mo3(CO)6(μ-PyS)2(μ3-PyS)2]
    石有茂
    陆世维
    郭和夫
    施剑秋
    吴锵金
    Chinese Science Bulletin, 1994, (03) : 263 - 264
  • [26] Co3O4 Supported on β-Mo2C with Different Interfaces for Electrocatalytic Oxygen Evolution Reaction
    Zhang, Jiaxin
    Li, Sisi
    Liu, Xiaohan
    Zheng, Haoquan
    Zhang, Wei
    Cao, Rui
    CHEMSUSCHEM, 2023, 16 (19)
  • [27] Synthesis, Crystal Structure and Properties of a New Heptamolybdate (NH4)6H2[Cu(C2O4)2(Mo7O24)] • 9H2O
    Li, J.
    Liu, Y.
    Luo, J.
    Zhao, J. W.
    Ma, P. T.
    Niu, J. Y.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (11) : 849 - 853
  • [28] SYNTHESIS　OF　CHIRAL　TETRAHEDRAL　TRANSITION　METAL　CARBONYL　CLUSTERS　SFeCoM（CO）8（RCOCp）(M＝Mo，W;R＝H，CH3，C2H5O)AND　THE　CRYSTAL　STRUCTURE　OF　SFeCoW（CO）8（C2H5O2CCp）
    He Ping Wu and Yuan Qi YIN(Lanzhou Institute of Chemical Physics
    Chinese Chemical Letters, 1994, (11) : 987 - 990
  • [29] SYNTHESES AND STRUCTURAL STUDIES OF Mo-Fe-S-CLUSTER COMPOUNDS Ⅶ.SPECTROSCOPIC STUDY OF THE [MoFe3S4] CUBANE UNIT IN （Bt4N）4(Mo2Fe Sa（SR）12] AND RELATED COMPOUNDS
    Liu Hanqin Kang Beisheng Cai Jinghua Huang Liangren Wu Daxu Hang Fang Quo Zhi Cong Aizen Lu JiaxiFujian Institute of Research on the Structure of Matter and Fuzhou Laboratory for Structural Chemistry
    结构化学, 1988, (03) : 171 - 180
  • [30] Infrared spectroscopic study of SO42- ions included in M2′M"(SeO4)2•6H2O (Me′ = K, NH4+; M" = Mg, Co, Ni, Cu, Zn) and NH4+ ions included in K2M(XO4)2•6H2O (X = S, Se; M" = Mg, Co, Ni, Cu, Zn)
    Marinova, D.
    Karadjova, V.
    Stoilova, D.
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 134 : 526 - 534
12345