SYNTHESIS AND CRYSTAL STRUCTURE OF THE Mo(O) TRINUCLEAR COMPLEXES: (Et4N)2[(CO)4Mo(μ-S)2-M(μ-S)2Mo(CO)4] (Ⅰ: M=Mo, Ⅱ: M=W)

被引：0

作者：

萧泰

余佩华

庄伯涛

机构：

[1] Northwest Normal University

[2] Fujian Institute of Research on the Structure of Matter

[3] Academia Sinica

[4] PRC

[5] Department of Chemistry

[6] Lanzhou 730070

[7] Fuzhou 350002

来源：

Chinese Science Bulletin | 1992年 / 19期

关键词：

SYNTHESIS AND CRYSTAL STRUCTURE OF THE Mo; TRINUCLEAR COMPLEXES; M=W; Et4N; M; CO;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The complexes of lower valent molybdenum have special nature in the form of coordination and the changeability of valent state. In order to further investigate it, we synthesised the title compounds Ⅰ and Ⅱ which were trinuclear complexes containing M(O)and determined their crystal structure.

引用

页码：1669 / 1670

页数：2

共 50 条

[1] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE MO(O) TRINUCLEAR COMPLEXES - (ET4N)2[(CO)4MO(MU-S)2-M(MU-S)2MO(CO)4] (I-M = MO, II-M = W)
XIAO, T
YU, PH
ZHUANG, BT
CHINESE SCIENCE BULLETIN, 1992, 37 (19): : 1669 - 1670
[2] Convenient synthesis of [Et4N]2[M2(CO)8(μ-H)2] (M = Mo, W)
Lin, JT
Huang, PH
ORGANOMETALLICS, 1998, 17 (16) : 3619 - 3620
[3] SYNTHESIS AND CHARACTERIZATION OF [ET4N]2[MO(CO)4(SPH)2] [ET4N]2[MO(CO)4(SBZ)2] - PRELIMINARY COMMUNICATION
ROSENHEIN, LD
NEWTON, WE
MCDONALD, JW
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 288 (01) : C17 - C21
[4] M(CO)4[2-(2′-pyridyl)benzimidazole] complexes; M = Mo or W
Khalil, MMH
TRANSITION METAL CHEMISTRY, 2000, 25 (03) : 358 - 360
[5] M(co)4[2-(2″-Pyridyl)Benzimidazole] Complexes; m = mo or w
Mostafa M. H. Khalil
Transition Metal Chemistry, 2000, 25 : 358 - 360
[6] A NEW MOLYBDENUM-TUNGSTEN-SULFUR CLUSTER COMPLEX FAMILY, [((OC)(4)M)(X)M'S-4](2-) (M=MO OR W, M'=MO OR W, X=1,2) - SYNTHESIS, STRUCTURE AND PROPERTIES OF A NEW TRINUCLEAR MIXED-VALENCE MO-S CLUSTER, [ET(4)N](2)[(OC)(4)MOS2MOS2MO(CO)(4)]
ZHUANG, BT
YU, PH
HUANG, LG
HE, LJ
LU, JX
POLYHEDRON, 1994, 13 (01) : 125 - 131
[7] Crystal structure of tetraethylammonium bis(tetracarbonylmolybdenum)-tetrathiotungstate, [Et4N]2[(OC)4MoS2WS2Mo(CO)4] and synthesis, infrared spectra, 95Mo NMR spectra and cyclic voltammetry of new linear trinuclear Mo(W)-S carbonyl clusters containing mixed-valence metal atoms [(OC)4MS2M′SM(CO)4]2- (M, M′ = Mo or W)
Zhuang, BT
Yu, PH
He, LJ
Huang, LR
Pan, GH
POLYHEDRON, 1998, 17 (25-26) : 4393 - 4402
[8] Reactivity of the Mo(O)(S) functional group in the [(L)Mo(O)(μ-S)2Mo(O)(S)]n- dimeric thiomolybdate complexes (L = C5H5-, n = 1; S42-, n = 2) and implications regarding the function of xanthine oxidase. Synthesis and structural characterization of [(DMF)3Mo(O)(μ-S)2Mo(O)(S2)], [Ph4P][(C5H5)Mo(O)(μ-S)2Mo(O)(S2) ], [Ph4P]2[(S4)Mo(O)(μ-S)2Mo(O)(S)], and (Et4N)4{[(S4)Mo(O)(μ-S)2Mo(O)(S)]2 $RT BC
Coucouvanis, D.
Toupadakis, A.
Lane, J.D.
Koo, S.M.
Kim, C.G.
Hadjikyriacou, A.
Journal of the American Chemical Society, 1991, 113 (14):
[9] Alkynyl Ti-M complexes based on M(CO)4 and MO2 building blocks (M = Mo, W)
Hildebrandt, Alexander
Mansilla, Noelia
Rheinwald, Gerd
Rueffer, Tobias
Lang, Heinrich
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (20) : 3231 - 3237
[10] FORMATION OF THE (MO(S2)2) (M = MO, W) MOIETY BY A MO4(2)-POLYSULFIDE REACTION - SYNTHESIS AND STRUCTURE OF MO(S2)2(BPY)
CHAKRABARTY, PK
BHATTACHARYA, S
PIERPONT, CG
BHATTACHARYYA, R
INORGANIC CHEMISTRY, 1992, 31 (17) : 3573 - 3577

← 1 2 3 4 5 →