Synthesis and Structure of K6H7〔Dy(SiMo6W5O39)2〕·10H2O

被引：0
作者：
WANG Xiao-Guang(Department of Chemistry
CHU Wen-Ling
WU Yue
XING Yan
LIN Yong-Hua
BAI Shi-Ying(Changchun Institute of Applied Chemistry
机构：
来源：
结构化学 | 1997年 / 03期
关键词：
synthesis; lanthanide; crystal structure; heteropoly compound;
D O I：
10.14102/j.cnki.0254-5861.1997.03.016
中图分类号：
O614 [金属元素及其化合物];
学科分类号：
070301 ; 081704 ;
摘要：
K6H7 [Dy(SiMo6W5O39)2] 10H2O, Mr= 4878. 5, is triclinic, sapcegroup P1 with a= 22. 697(5) A; b= 12. 835(4) A; c= 18. 216(6) A; a= 90. 56(2); β= 98. 24(2); γ= 90. 51 (2)°；V= 5251 (2) A3； Z= 2, Dc= 3.08 g/cm3; F(000) = 4321; S = 1. 550, μ= 183.65 cm-1. Refinement resulted in a final R of0.091, based on 7816 with I>3δ independent renections. The structure contains discrete [Dy (SiW5Mo6O39) 2] 13 - anions. The orientations fo the W and Mo atoms are random in the crystal. The MO6 octahedron and SiO4 tetrahedron are somewhat distorted.
引用
收藏
页码：233 / 238
页数：6
相关论文
共 50 条
  • [21] SYNTHESIS, CHARACTERIZATION, AND CRYSTAL STRUCTURE OF A NOVEL DECAVANADATE Mg(H2O)6(C6H14N2)2V10O28·8H2O
    R. Ksiksi
    I. Jendoubi
    H. Chebbi
    M. Graia
    M. F. Zid
    Journal of Structural Chemistry, 2021, 62 : 1243 - 1250
  • [22] Crystal structure of the bioctahedral cluster complex K6[Re12CS17(CN)6]•2CH3OH•10H2O
    Mironov, Yu. V.
    Kim, S. -J.
    Fedorov, V. E.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 50 (02) : 365 - 367
  • [23] New Quaternary Alkali-Metal Hypodiphosphate Hydrates: Preparation, Crystal Structure, Vibrational Spectrum, and Thermal Behavior of K4P2O6•8H2O and Na2K2P2O6•8H2O in Comparison to Na4P2O6•10H2O
    Gjikaj, Mimoza
    Wu, Peng
    Brockner, Wolfgang
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (12-13): : 2144 - 2149
  • [24] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
    Zheng, YQ
    Kong, ZP
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
  • [25] Synthesis and Structure of K3Na3〔MnMo9O32〕·6H2O
    YANG Xi--Ping
    SHAO Shi--Bao
    CHEN Chang-Zhang
    HUANG Xiao--Ying
    LIN Zhou--Bin
    Gao Dong--Shou (Fujian Institute of Research on the Structure of Matter
    结构化学, 1997, (01) : 64 - 67
  • [26] Synthesis and structural studies of [Na(C7H6O4)(H2O)3](C7H5O4) • 2H2O
    Kula, Alina
    Rzaczynska, Zofia
    Mazur, Liliana
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2008, 38 (10) : 723 - 728
  • [27] Synthesis and Crystal Structure of a Novel Compound of （C2N2H8O2） H6V10O28
    Ju Tao LIU
    Chinese Chemical Letters, 2004, (07) : 859 - 862
  • [28] Crystal structure of the bioctahedral cluster complex K6[Re12CS17(CN)6]·2CH3OH·10H2O
    Yu. V. Mironov
    S. -J. Kim
    V. E. Fedorov
    Journal of Structural Chemistry, 2009, 50 : 365 - 367
  • [29] Synthesis and thermochemistry of SrB2O4•2.5H2O and SrB6O10•5H2O
    Huang, Hong-Sheng
    Liu, Zhi-Hong
    THERMOCHIMICA ACTA, 2007, 463 (1-2) : 87 - 89
  • [30] Octahedral aqua fluoride rhenium cluster complexes K[Re6S8F3(H2O)3]•7H2O, H3O[Re6Se8F3(H2O)3]•7H2O and [Re6Q8F2(H2O)4]•12H2O (Q = S, Se):: Synthesis and structure
    Mironov, Yuri V.
    Yarovoi, Spartak S.
    Naumov, Dmitrii Y.
    Simon, Arndt
    Fedorov, Vladimir E.
    INORGANICA CHIMICA ACTA, 2007, 360 (09) : 2953 - 2957
12345