Synthesis and Structure of K6H7〔Dy(SiMo6W5O39)2〕·10H2O

被引：0
|
作者：
WANG Xiao-Guang(Department of Chemistry
CHU Wen-Ling
WU Yue
XING Yan
LIN Yong-Hua
BAI Shi-Ying(Changchun Institute of Applied Chemistry
机构：
来源：
结构化学 | 1997年 / 03期
关键词：
synthesis; lanthanide; crystal structure; heteropoly compound;
D O I：
10.14102/j.cnki.0254-5861.1997.03.016
中图分类号：
O614 [金属元素及其化合物];
学科分类号：
070301 ; 081704 ;
摘要：
K6H7 [Dy(SiMo6W5O39)2] 10H2O, Mr= 4878. 5, is triclinic, sapcegroup P1 with a= 22. 697(5) A; b= 12. 835(4) A; c= 18. 216(6) A; a= 90. 56(2); β= 98. 24(2); γ= 90. 51 (2)°；V= 5251 (2) A3； Z= 2, Dc= 3.08 g/cm3; F(000) = 4321; S = 1. 550, μ= 183.65 cm-1. Refinement resulted in a final R of0.091, based on 7816 with I>3δ independent renections. The structure contains discrete [Dy (SiW5Mo6O39) 2] 13 - anions. The orientations fo the W and Mo atoms are random in the crystal. The MO6 octahedron and SiO4 tetrahedron are somewhat distorted.
引用
收藏
页码：233 / 238
页数：6
相关论文
共 50 条
  • [11] Synthesis and Crystal Structure of Na10[LaSiW11O39（H2O）4]2·22H2O
    ZHAO Shi-Long ZHANG Han-Hui② HUANG Chang-Cang LIN Zheng-ZhongSUN Rui-Qing ZHENG Xiao-Ling LIN Zhi-Hua WU Xiao-Yuan (Department of Chemistry
    结构化学, 2001, (06) : 451 - 454
  • [12] Hydrothermal Synthesis and Electrochemical Property of Self-Assembly K10 [H2W12O42]•10H2O Nanorod
    Kong, Xingang
    Li, Wen
    Cao, Liyun
    Huang, Jianfeng
    Wu, Jianpeng
    Fei, Jie
    Li, Jiayin
    NANO, 2016, 11 (06)
  • [13] Synthesis and crystal structure of Na10[LaSiW11O39(H2O)4]2•22H2O
    Zhao, SL
    Zhang, HH
    Huang, CC
    Lin, ZZ
    Sun, RQ
    Zheng, XL
    Lin, ZH
    Wu, XY
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (06) : 451 - 454
  • [14] A novel decamolybdodivanadate:: synthesis and crystal structure of [H3O+]2Na6[Mo10VIV2IVO38] • 7H2O
    Yang, WB
    Lu, CZ
    Zhuang, HH
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (10) : 865 - 868
  • [15] Synthesis and crystal structure of (1-C10H7-NH3)6P6O18•2H2O
    Ben Nasr, C
    Saïd, I
    Rzaigui, M
    MATERIALS RESEARCH BULLETIN, 2001, 36 (5-6) : 789 - 798
  • [16] Synthesis and crystal structure of [Ni(C5H5N)2(C7H6O2N)2]•H2O
    Jiang, YM
    Zhang, SH
    Xiao, Y
    Zhong, XX
    Zhou, ZY
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (03) : 355 - 358
  • [17] Hydrothermal synthesis and structure of K3Na5(H2NCH2CH2NH3)2{(VO)12O6[B3O6(OH)]6}(H2O)•12H2O
    Lu, B
    Wang, H
    Zhang, L
    Dai, CY
    Cai, QH
    Shan, YK
    CHINESE JOURNAL OF CHEMISTRY, 2005, 23 (02) : 137 - 143
  • [18] Synthesis　and　Crystal　Structure　of　K8H5［La(SiW2Mo9O39)2（H2O）17］4H2O
    Lu Bin (Department of Chemistry
    Wu Yue
    Xing Yan
    Lin Yong-Hua
    Bai Shi-Ying (Changchun Institute of Applied Chemistry
    结构化学, 1996, (04) : 301 - 306
  • [19] SYNTHESIS, CHARACTERIZATION, AND CRYSTAL STRUCTURE OF A NOVEL DECAVANADATE Mg(H2O)6(C6H14N2)2V10O28•8H2O
    Ksiksi, R.
    Jendoubi, I.
    Chebbi, H.
    Graia, M.
    Zid, M. F.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (08) : 1243 - 1250
  • [20] Synthesis, structure and characterization of layered Ca[B(C6H6O7)2](H2O)4•HCl
    Wu, Hongping
    Pan, Shilie
    Yu, Hongwei
    Huang, Zhenjun
    Jia, Dianzeng
    JOURNAL OF MOLECULAR STRUCTURE, 2012, 1027 : 111 - 115
12345