Synthesis and Structure Investigation of a Transition Metal Ion Bridging Bis(diphosphopentamolybdates),[H2BIIM]3[HBIIM]4[Mn(H2O)4(P2Mo5O23)2]·7H2O

被引：6
|
作者：
魏林恒 [1 ]
王子梁 [2 ]
赵俊伟 [2 ]
王敬平 [2 ]
机构：
[1] Institute of Natural Resources and Environmental Science,College of Environment and Planning,Henan University
[2] College of Chemistry and Chemical Engineering,Henan University
来源：
结构化学 | 2010年 / 29卷 / 05期
关键词：
polyoxometalate; molybdate; crystal structure; dumbbell-like; phosphate;
D O I：
10.14102/j.cnki.0254-5861.2010.05.023
中图分类号：
O621.25 [];
学科分类号：
摘要：
A novel transition metal ion bridging bis(diphosphopentamolybdates) has been synthesized and characterized by elemental analysis,IR spectrum,UV spectrum and single-crystal X-ray diffraction.The single-crystal structure analysis shows that the compound consists of seven charge-compensating 2,2’-biimidazole cations (BIIM=2,2’-biimidazole) and one dumbbell-like [Mn(H2O)4(P2Mo5O23)2]10-heteropolyanion which is constructed by two [P2Mo5O23]6-clusters bridged through one [Mn(H2O)4]2+ cation.
引用
收藏
页码：784 / 788
页数：5
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