Synthesis and Crystal Structure of 4,4'-(4-(1-Naphthyl)-4-phenyl-1,3-butadienylidene)-bis[N,N-diethylbenzenamine]

被引：0
|
作者：
LI Xiang-Gao② WU An-Shu XU De-Shun WANG Shi-Rong ZHAO Xue-Ming (Fine Chemicals Department
机构：
来源：
Chinese Journal of Structural Chemistry | 2006年 / 09期
关键词：
4; 4’-(4-(1-naphthyl)-4-phenyl-1; 3-butadienylidene)-bis[N; N-diethyl-benzenamine; synthesis; crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2006.09.008
中图分类号：
O621.25 [];
学科分类号：
070303 ; 081704 ;
摘要：
The title compound (C40H42N2) has been synthesized by the reaction of 1-(1- naphthyl)-1-phenyl-3-chloropropylene and bis(4-(diethylamino) phenyl)methanone, and charac- terized by IR, 1H NMR, MS and X-ray diffraction analysis. The crystal belongs to the monoclinic system, space group P21/c with a = 17.047(3), b = 10.807(2), c = 18.494(4) , β = 105.727(4)°, V = 3279.4(11) 3, Mr = 550.76, Z = 4, Dc = 1.115 g/cm3, μ(MoKα) = 0.085 mm-1, F(000) = 1184, the final R = 0.0625 and wR = 0.1384 for 2276 observed reflections (I > 2σ(Ι)). X-ray analysis reveals that the butadiene fragment adopts a planar cisiod conformation and makes a dihedral angel of 69.4(2)° with the naphthalene ring.
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页码：1063 / 1066
页数：4
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