Syntheses,Crystal Structures and Electrochemical Properties of Two Molybdophosphates

被引：1

作者：

于洋 ^{[1
]}

于凯 ^{[1
,2
]}

周百斌 ^{[1
,2
]}

赵志凤 ^{[1
,3
]}

苏占华 ^{[1
]}

机构：

[1] Key Laboratory of Physical and Chemical Materials,College of Heilongjiang Province,Harbin Normal University

[2] Department of Applied Chemistry,Harbin Institute of Technology

[3] Department of Applied Chemistry, Harbin Institute of Technology

来源：

结构化学 | 2010年 / 29卷 / 10期

基金：

中国国家自然科学基金;

关键词：

molybdophosphates; hydrothermal synthesis; crystal structure; electrochemical property;

D O I：

10.14102/j.cnki.0254-5861.2010.10.008

中图分类号：

O621.13 [];

学科分类号：

070303 ; 081704 ;

摘要：

Two molybdophosphate compounds,[Ni(bim)3]2[H2P2Mo5O23]·2H2O 1 and [Zn(bpy)2]2[Zn(bpy)(H2O)]2Zn[Mo6O12(OH)3(HPO4)4]2·9H2O 2 (bim = 2,2’-biimidazole,bpy = 2,2’-dipyridyl),have been synthesized under hydrothermal conditions and structurally characterized by elemental analysis,TG,and IR. The single-crystal X-ray analysis exhibits that 1 consists of one [H2P2Mo5O23]4-,two [Ni(bim)3]2+ cations and two lattice water molecules,while 2 is constructed from one sandwich-type [ZnP4Mo6] anion modified by four Zn-bpy complexes and nine lattice water molecules. The electrochemical behaviors of compounds 1 and 2 have been studied in detail based on solid bulk modified carbon paste electrodes of compound (CPEs).

引用

页码：1505 / 1512

页数：8

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