Highly efficient Zr doped-TiO2/glass fiber photocatalyst and its performance in formaldehyde removal under visible light

被引:9
作者
Chao Huang [1 ]
Yaping Ding [1 ]
Yingwen Chen [1 ,2 ]
Peiwen Li [3 ]
Shemin Zhu [4 ]
Shubao Shen [1 ]
机构
[1] State Key Laboratory Materials of Materials-Oriented Chemical Engineering, Nanjing Tech University
[2] Jiangsu Engineering Technology Research Center of Environmental Cleaning Material, School of Environmental Science and Engineering,Nanjing University of Information Science and Technology
[3] Department of Aerospace and Mechanical Engineering, the University of Arizona
[4] College of Material Science and Engineering, Nanjing Tech University
关键词
TiO2; Zr; Photocatalyst; Formaldehyde; Glass fiber;
D O I
暂无
中图分类号
O643.36 [催化剂]; O644.1 [光化学];
学科分类号
070304 ; 081704 ; 081705 ;
摘要
Zr-doped-TiO2loaded glass fiber(ZT/GF) composite photocatalysts with different Zr/Ti ratios were prepared with a sol–gel process. Zr4+can replace Ti4+in the TiO2lattice, which is conducive to forming the anatase phase and reducing the calcination temperature. The glass fiber carrier was responsible for better dispersion and loading of Zr-doped-TiO2particles, improving the applicability of the Zr-doped-TiO2. The ZT/GF photocatalysts were characterized by X-ray diffraction(XRD), scanning electron microscope(SEM), Fourier transform infrared spectroscopy(FT-IR), ultraviolet–visible spectroscopy(UV–vis) and Barrett–Joyner–Halenda(BJH). The performance of photocatalysts with different loading was evaluated in formaldehyde degradation under visible light at room temperature. ZT/GF0.2exhibited the highest activity, with a formaldehyde removal rate as high as 95.14% being observed, which is better than that of the photocatalyst particles alone. The stability of the catalyst was also tested, and ZT/GF exhibited excellent catalytic performance with 94.38%removal efficiency, even after seven uses.
引用
收藏
页码:61 / 69
页数:9
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