Ethylene Oligomerization by 8-Aminoquinoline Nickel Dichloride Complex Supported on β-Cyclodextrin

被引：0
|
作者：
陈湧
朱宁
李子龙
孙文华
机构：
[1] Beijing 100080
[2] China
[3] Chinese Academy of Sciences
[4] Institute of Chemistry
[5] State Key Laboratory of Engineering Plastics and the Center for Molecular Sciences
来源：
ChineseJournalofChemistry | 2003年 / 05期
关键词：
ethylene oligomerization; supported catalyst; β cyclo dextrin;
D O I：
暂无
中图分类号：
O643.3 [催化];
学科分类号：
081705 ;
摘要：
Cyclodextrin was pretreated by methylaluminoxane (MAO) and subsequently reacted with 8 aminoquinoline nickel dichloride complex to yield the supported catalyst, which was characterized by ICP, IR and XPS methods. Using MAO as cocatalyst, the catalytic activity of this supported catalyst was investigated at various reaction temperature and Al/Ni molecular ratio. The results showed that, despite possessing a number of polar groups, the supported catalyst displayed relatively high activity over 1×10 5 g ethylene/(mol Ni·h) under mild conditions.
引用
收藏
页码：491 / 493 +475
页数：4
相关论文
共 50 条
  • [1] Ethylene oligomerization by 8-aminoquinoline nickel dichloride complex supported on β-cyclodextrin
    Chen, Y
    Zhu, N
    Li, ZL
    Sun, WH
    CHINESE JOURNAL OF CHEMISTRY, 2003, 21 (05) : 491 - 493
  • [2] Combination of 8-aminoquinoline nickel dichloride and Cp2ZrCl2 catalysts for ethylene polymerization
    Li, ZL
    Zhu, N
    Sun, WH
    Shao, CX
    Ke, YC
    Hu, YL
    He, JS
    POLYMER INTERNATIONAL, 2001, 50 (12) : 1275 - 1278
  • [3] ETHYLENE OLIGOMERIZATION BY SUPPORTED NICKEL-COMPLEXES
    NESTEROV, GA
    FINK, G
    ZAKHAROV, VA
    MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1989, 10 (12): : 669 - 673
  • [4] SUPPORTED NICKEL-CATALYSTS FOR ETHYLENE OLIGOMERIZATION
    NESTEROV, GA
    ZAKHAROV, VA
    FINK, G
    FENZL, W
    JOURNAL OF MOLECULAR CATALYSIS, 1991, 69 (01): : 129 - 136
  • [5] Formation of new monomeric Pd(III) complex species with 8-aminoquinoline
    Nichkova, M
    Mitewa, M
    RESEARCH ON CHEMICAL INTERMEDIATES, 2000, 26 (05) : 483 - 488
  • [6] MECHANISTIC STUDIES OF NICKEL(II)-CATALYZED DIRECT ALCOHOLYSIS OF 8-AMINOQUINOLINE AMIDES
    Morimoto, Hiroyuki
    Akkad, Walaa
    Deguchi, Toru
    Ohshima, Takashi
    HETEROCYCLES, 2020, 101 (02) : 471 - 485
  • [7] Formation of new monomeric Pd(III) complex species with 8-aminoquinoline
    M. Nichkova
    M. Mitewa
    Research on Chemical Intermediates, 2000, 26 : 483 - 488
  • [8] Tandem ethylene oligomerization and Friedel?Crafts alkylation of toluene catalyzed by hyperbranched nickel complex and ethylaluminium dichloride
    Wang, Jun
    Hou, Shuang
    Wang, Li-bo
    Huo, Hong-liang
    Zhang, Na
    Shi, Wei-guang
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2020, 57 (01): : 55 - 61
  • [9] A NEW NICKEL-COMPLEX FOR THE OLIGOMERIZATION OF ETHYLENE
    PEUCKERT, M
    KEIM, W
    ORGANOMETALLICS, 1983, 2 (05) : 594 - 597
  • [10] Selective Oligomerization of Ethylene Catalyzed by Nickel Complex
    Zhao, Qing
    Hu, Suling
    Wu, Wei
    Yuan, Dandan
    Mao, Guoliang
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2024, 40 (06): : 163 - 170
12345