An improved synthesis of bis(cyclopentadienone)

被引:0
|
作者
Ming Ming Yu~(a
机构
基金
中国国家自然科学基金;
关键词
Bis(cyclopentadienone); Friedel-Crafts reaction; Oxidation; Condensation;
D O I
暂无
中图分类号
O621.3 [有机合成化学];
学科分类号
摘要
An improved strategy for the synthesis of 3,3’-(oxy-p-phenylene)bis(2,4,5-triphenylcyclopentadienone) was developed,which includes three steps:Friedel-Crafts reaction,oxidation and condensation.Importantly,the use of KMnO;made the second step simple and efficient,which has potential application to synthesis of bis(cyclopentadienone)s.The course of oxidation has been confirmed by isolated intermediates.
引用
收藏
页码:1157 / 1161
页数:5
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