SYNTHESIS, CHARACTERIZATION AND SOME PROPERTIES OF EPOXY RESINS CONTAINING AZOMETHINE BONDING

被引:0
作者
smet Kaya [1 ]
Murat Gül [1 ]
机构
[1] anakkale Onsekiz Mart University, Faculty of Sciences and Arts, Department of Chemistry, Polymer Research Laboratory
关键词
Epoxy resin; Thermal analysis; Poly(imine)s;
D O I
暂无
中图分类号
TQ433.437 [];
学科分类号
0817 ;
摘要
New epoxy resins were prepared from hydroxyl substituted Schiff base monomers in two steps. The first step is based on the synthesis of hydroxyl substituted Schiff base monomers via condensation reaction. The second step includes the reaction between Schiff base monomers with epichlorohydrine (EPC) to obtain epoxy resins. The structures of resulting compounds were confirmed by FTIR and 1H-NMR. TG-DTA and DSC measurements were made for thermal characterizations of the compounds. Chemical resistances of the cured epoxy-amine systems in acidic, alkaline and organic solvents were determined for coating applications. HCl (aqueous solution, 10%), NaOH (aqueous solution, 10%), DMSO, DMF, N-methylpyrrolidone, ethanol, THF and acetone were used for corrosion tests. Chemical resistance data show that the synthesized resins have good chemical resistance against various acid, alkaline and common organic solvents.
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页码:1087 / 1095
页数:9
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