Synthesis and photophysical properties of donor–acceptor system based bipyridylporphyrins for dye-sensitized solar cells

被引：0

作者：

Preeyanut Duanglaor ^{[1
]}

Preecha Thiampanya ^{[1
]}

Taweesak Sudyoadsuk ^{[2
]}

Vinich Promarak ^{[2
]}

Buncha Pulpoka ^{[1
]}

机构：

[1] Supramolecular Chemistry Research Unit and Organic Synthesis Research Unit,Department of Chemistry,Faculty of Science,Chulalongkorn University

[2] Department of Materials Science & Engineering,School of Molecular Science and Engineering,Vidyasirimedhi Institute of Science and Technology (VISTEC)

来源：

Journal of Energy Chemistry | 2015年 / 06期

关键词：

Dye-sensitized solar cells(DSSCs); Porphyrin; Ruthenium complex; Energy;

D O I：

暂无

中图分类号：

O641.4 [络合物化学（配位化学）]; TM914.4 [太阳能电池];

学科分类号：

070304 ; 080502 ; 081704 ;

摘要：

Bipyridylporphyrin derivatives possessing a porphyrin moiety as the electron donor and bipyridyl moiety as the electron–acceptor were designed and synthesized for dye-sensitized solar cells（DSSCs）. The photophysical and electrochemical properties were investigated by absorption spectrometry and cyclic voltammetry. Density functional theory（DFT） was employed to study electron distribution. From the photovoltaic performance measurements, a maximum conversion efficiency（η） of 0.38% was achieved based on the bipyridylporphyrin ruthenium dye A7(J= 1.33 mA/cm, V= 0.45 V, FF = 0.64) under 1.5 irradiation（100 mW/cm）.

引用

页码：779 / 785

页数：7