Hydrothermal Syntheses, Crystal Structures and Luminescence Properties of Cu(Ⅱ) and Cd(Ⅱ) Complexes Assembled by 6-Hydroxypicolinic Acid and 1,10-Phenanthroline

被引：1

作者：

郁有祝 ^{[1
]}

常颂扬 ^{[1
]}

韩曦 ^{[1
]}

陈广鑫 ^{[1
]}

轩亚威 ^{[1
]}

武现丽 ^{[2
]}

王芳 ^{[1
]}

机构：

[1] College of Chemistry and Environmental Engineering,Anyang Institute of Technology

[2] College of Chemistry and Molecular Engineering,Zhengzhou University

来源：

ChineseJournalofStructuralChemistry | 2019年 / 38卷 / 04期

基金：

中国国家自然科学基金;

关键词：

Cu(Ⅱ) and Cd(Ⅱ) complexes; 6-hydroxypicolinic acid; crystal structures; luminescent properties;

D O I：

10.14102/j.cnki.0254-5861.2011-2105

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

Two new complexes based on 6-hydroxypicolinic acid（H;picO） and 1,10-phenanthroline（phen）, such as [Cu;（picO）;（phen）;]·12 H;O（1） and {[Cd;（picO）;（phen）;（H;O）;]·5H;O};（2）, have been synthesized and characterized by IR, elemental analyses, thermogravimetric analyses and X-ray diffraction technique. Single-crystal X-ray diffraction analyses revealed that the two complexes both crystallize in the triclinic system, space group P（16）-. For complex 1, the picO ligands adopt a tridentate coordination mode to link copper（Ⅱ） ions into dimmers. PicO ligands also adopt a tridentate mode in complex 2, which connects the cadmium（Ⅱ） to form a one-dimensional chain. Moreover, luminescent properties of 1 and 2 were also investigated.

引用

页码：651 / 659

页数：9

共 8 条

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