GaI3 Catalyzed Tetrahydropyranylation of Alcohols and Phenols

被引:2
|
作者
孙培培
胡志新
机构
[1] College of Chemistry and Environmental Science
[2] Nanjing Normal University
[3] Jiangsu 210097
[4] China
关键词
gallium triiodide; alcohol or phenol; 2-alkoxy(aryloxy)tetrahydropyran; the protection of hydroxyl group;
D O I
暂无
中图分类号
O643.3 [催化];
学科分类号
081705 ;
摘要
In dichloromethane, the nucleophilic addition of alcohols or phenols to 3,4-dihydro-2H-pyran (DHP) was cata-lyzed effectively by gallium triiodide which was generated in situ by the reaction of gallium metal and iodine to give the corresponding tetrahydropyranyl acetals in good to excellent yields.
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页码:1341 / 1343
页数:3
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