Highly Selective Diphoshinoamine/Cr(III) Catalysts for Ethylene Tetramerization

被引:0
作者
Tao JIANG1
机构
关键词
Ethylene tetramerization; 1-octene; Cr(III); diphoshinoamine; MAO; catalyst;
D O I
暂无
中图分类号
O643.32 [催化反应];
学科分类号
081705 ;
摘要
Two novel diphoshinoamine ligands have been synthesized. Combination of Cr(III) and methylaluminoxane(MAO) generated active catalytic system which can catalyze tetrame- rization of ethylene with high catalytic activity up to 2.5×106 g/mol Cr.h and high selectivity to produce 1-octene (C8 in products is being 89.80 wt%).
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页码:358 / 360
页数:3
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