Synthesisandcrystalstructureof[Y（C5Me4SiMe3）{μ-O（CH2）3CH3}{N（SiHMe2）2}]2

被引：0

作者：

罗云杰 ^{[1
]}

冯晓莹 ^{[1
,2
]}

机构：

[1] Organometallic Chemistry Laboratory,Ningbo Institute of Technology,Zhejiang University

[2] Department of Polymer Science and Engineering,Zhejiang University

来源：

Journal of Rare Earths | 2011年 / 29卷 / 01期

关键词：

yttrium amide complex; ring-opening reaction of THF; synthesis; crystal structure; rare earths;

D O I：

暂无

中图分类号：

TG146.45 [];

学科分类号：

080502 ;

摘要：

A dimeric yttrium complex [Y(C5Me4SiMe3){μ-O(CH2)3CH3}{N(SiHMe2)2}]2 (1) was isolated as one of the byproducts from the reaction of Y{N(SiHMe2)3}3(THF)2 with C5Me4HSiMe3 in 1:1.1 molar ratio in toluene at 100 C for 2 d.Complex 1 was characterized by elemental analysis,NMR spectroscopy,FT-IR spectroscopy,and X-ray single crystal structure analysis.X-ray diffractions revealed that com-plex 1 was a symmetric dimer,and the center metal Y3+ was six-coordinated by one nitrogen atom from the amide group,two bridging oxy-gen atoms from the O(CH2)3CH3 groups,and one cyclopentadienyl ring in 5-fashion to adopt a distorted tetrahedron geometry.The forma-tion of complex 1 was postulated to be a result from C-O bond cleavage reaction of THF.

引用

页码：24 / 27

页数：4

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