One-pot tandem Barbier-Prins synthesis of tetrahydropyrans in aqueous media

被引：0
|
作者：
WEN Meijiao
机构：
来源：
Science in China(Series B:Chemistry) | 2005年 / 01期
关键词：
Barbier-type; Prins-cyclization; tetrahydropyran; water; environment benign;
D O I：
暂无
中图分类号：
O621 [有机化学一般性问题];
学科分类号：
070303 ; 081704 ;
摘要：
By investigating the effect of the amount of water, the ratio of aldehyde and allyl- bromide, and the reaction temperature on the transformation, 2,4,6-trisubstituted tetrahydro- pyrans are synthesized by a novel tandem Barbier-Prins-cyclization reaction in the presence of micro-amount of water under mild conditions. The experiment is easy to perform without the need to exclude moisture or air. The reaction is atomic economical and environmentally benign.
引用
收藏
页码：38 / 41
页数：4
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