The reversible addition-fragmentation chain transfer(RAFT) miniemulsion polymerization of vinyl acetate mediated by xanthate

被引：0
|
作者：
Bo Jiang
机构：
来源：
Chinese Chemical Letters | 2009年 / 20卷 / 06期
基金：
中国国家自然科学基金;
关键词：
Viny1; acetate; Xanthate; Reversible addition-fragmentation chain transfer; Miniemulsion;
D O I：
暂无
中图分类号：
O631.3 [高聚物的化学性质];
学科分类号：
摘要：
The reversible addition-fragmentation chain transfer(RAFT) miniemulsion polymerization of vinyl acetate(VAc) mediated by methyl(methoxycarbonothioyl) sulfanyl acetate(MMSA) was carried out.The results showed that polymerizations initiated by AIBN and KPS proceeded in a controlled way.The RAFT miniemulsion polymerization of VAc initiated by KPS showed the shorter inhibition period,higher propagation rate coefficient and final conversion than those in experiment initiated by AIBN.When the monomer conversion reached 25%,the polydispersity index(PDI) of polymer became broad,which was related to chain transfer reaction in RAFT miniemulsion of VAc.
引用
收藏
页码：733 / 737
页数：5
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