Synthesis and Crystal Structure of a Heterometallic Chain Coordination Polymer:{[Ni2Mn2L2(CH3CH2OH)(H2O)]·CH3OH·2H2O}n

被引：0
作者：
李付安 [1 ,2 ]
王守斌 [1 ]
陶偌偈 [1 ]
机构：
[1] Institute of Molecular & Crystal Engineering,Chemistry and Chemical Engineering College of Henan University
[2] College of Chemistry and Chemical Engineering,Pingdingshan University
来源：
结构化学 | 2010年 / 29卷 / 01期
关键词：
nickel; manganese; coordination polymer; crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2010.01.023
中图分类号：
O627.81 [];
学科分类号：
070303 ; 081704 ;
摘要：
A chain-like coordination polymer with the chemical formula of {[Ni2Mn2L2(CH3CH2OH)-(H2O)]·CH3OH·2H2O}n has been synthesized by the assembly reaction of K2NiL·H2O and Mn(OAC)2·4H2O with a 1:1 mole ratio in methanol,where OAC-=CH3COO-and H4L=2-hydroxy-3-[(E)-({2-[(2-hydroxybenzoyl)imino]ethyl}imino)methyl]benzoic acid.The crystal structure was determined by single-crystal X-ray diffraction analysis.It belongs to the triclinic system,space group P1,with a=9.9464(8),b=13.4718(11),c=14.3877(12),α=87.1930(10),β=85.4280(10),γ=74.6470(10)°,V=1852.4(3)3,Z=2,Dc=1.807g/cm3,Mr=1008.03,λ(MoKα)=0.71073,μ(MoKα)=1.794 mm-1,F(000)=1032,R=0.0527 and wR=0.1284(Ⅰ>2σ(Ⅰ)).The compound exhibits a chain-like structure formed by dissymmetrical tetranuclear units.
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收藏
页码：63 / 68
页数：6
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