EffectofrareearthNd3+dopingcontentsonphysical,structural,andmagneticpropertiesofCo-Nispinelferritenanoparticles

被引:0
作者
Junjiao Li [1 ]
Muhammad Yousaf [2 ]
Qaisar Hayat [3 ]
Muhammad Akbar [4 ]
Asma Noor [3 ]
MAK Yousaf Shah [2 ]
Fenghua Qi [5 ]
Yuzheng Lu [5 ]
机构
[1] Department of Electronic and Engineering,Nanjing Vocational Institute of Mechatronic Technology
[2] Energy Storage Joint Research Centre,School of Energy and Environment,Southeast University
[3] Shenzhen Key Laboratory of Laser Engineering,Guangdong Provincial Key Laboratory of Micro/Nano Optomechatronics Engineering,College of Physics and Optoelectronic Engineering,Shenzhen University
[4] Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials,Faculty of Physics and Electronic Science,Hubei University
[5] College of Electronic and Engineering,Nanjing Xiaozhuang University
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中图分类号
TB383.1 [];
学科分类号
070205 ; 080501 ; 1406 ;
摘要
Rare earth(RE) low doping has a significant influence on the structural,morphological,and magnetic properties of spinel ferrite nanoparticles.Therefore,rare earth neodymium(Nd) oxide was fully doped into spinel ferrite with a composition of Co0.80Ni0.20NdxFe2-xO4(x=0.0,0.05,0.10,and 0.15) using the sol-gel auto combustion method.Structural analysis of the synthesized samples with low doping of Nd using X-ray diffraction(XRD) and Rietveld refinements reveals a pure single-phase cubic structure,while the second phase appears with increasing content of Nd3+ at x=0.10 and 0.15.Scanning electron microscopy(SEM) and high-resolution transmission electron microscopy(HR-TEM) show well-shaped spherical grains within the nanometer range of the pure Co0.80Ni0.20Fe2O4 sample,while larger grains with the presence of agglomeration are observed with doping of Nd3+into the spinel ferrite nanoparticles.The magnetic parameters,i.e.,saturation magnetization Ms,remanence and magnetic moments exhibit decreasing trend with Nd3+doping and Ms values are in 65.69 to 53.34 emu/g range.The coercivity of the Nd-doped Co-Ni spinel ferrite sample was calculated to be 1037.76 to ~827.24 Oe.This work demonstrates remarkable improvements in the structural and magnetic characteristics of Nddoped Co-Ni spinel ferrite nanoparticles for multiple versatile applications.
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页码:1746 / 1753
页数:8
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