Voltammetric Study on the Complexes of the Rare Earths with Tetraphenylporphyrin

被引：0

作者：

黄云辉

高小霞

机构：

[1] Beijing 100871

[2] Department of Chemistry Peking University

[3] China

来源：

JournalofRareEarths | 1992年 / 04期

基金：

中国国家自然科学基金;

关键词：

Rare earths; Tetraphenylporphyrin; Voltammertric behaviors;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Fifteen rare earth-tetraphenylporphyrin(RE-TPP)complexes were directly prepared by mixing equalmolar concentrations of RE(ClO)and HTPP in acetone media.The electrochemical behaviors of these com-plexes and the influence of dissolved oxygen were investigated by voltammetry.Althrough there are some differ-ence between the behaviors of light and heavy rare earth-porphyrins,the central RE ions of the all fifteen com-plexes were reduced from tervalent to divalent state,meanwhile the dissovled oxygen was reduced as superoxideion O~-.which readily combined with the complex forming peroxide additive complex such as RE-TPP·O.

引用

页码：257 / 262

页数：6