Preparation and photocatalytic activity of B, Y co-doped nanosized TiO2 catalyst

被引:5
作者
石中亮 [1 ]
刘富梅 [1 ]
姚淑华 [1 ]
机构
[1] School of Applied Chemistry, Shenyang University of Chemical Technology
关键词
titanium dioxide; photocatalysis; co-doping; phenol; rare earths;
D O I
暂无
中图分类号
TB383.1 [];
学科分类号
070205 ; 080501 ; 1406 ;
摘要
The catalysts of un-doped, single-doped and co-doped titanium dioxide (TiO2) powders were prepared by sol-gel method with Ti(OC4H9)4 as a raw material. The photocatalytic decomposition of phenol in aqueous solution under UV light was used as a probe reaction to evaluate their photocatalytic activities. The effects of B, Y co-doping on the crystallite sizes, crystal pattern, surface composition, and optical property of the catalyst were investigated by thermogravimetric differential thermal analysis, X-ray diffraction (XRD), and diffuse reflectance UV-Vis spectroscopy (UV-Vis DRS). It was confirmed that co-doping TiO2 was activated by visible light and used as an effective catalyst in photooxidation reactions. The photocatalytic activity of B, Y co-doped TiO2 was markedly improved due to the cooperative actions of the two dopants.
引用
收藏
页码:737 / 741
页数:5
相关论文
共 8 条
  • [1] RE/TiO2用于NO2-光催化氧化的研究
    高远
    徐安武
    祝静艳
    刘汉钦
    [J]. 催化学报, 2001, (01) : 53 - 56
  • [2] Photodecolorization of methyl orange by yttrium incorporated TiO 2 supported ZSM-5[J] . Applied Catalysis B, Environmental . 2008 (1)
  • [3] Comparative study of the photocatalytic performance of boron–iron Co-doped and boron-doped TiO 2 nanoparticles[J] . Romana Khan,Sun Woo Kim,Tae-Jeong Kim,Chang-Mo Nam.Materials Chemistry and Physics . 2008 (1)
  • [4] Photocatalytic oxidation of 2,4,6-trichlorophenol in water using a cocurrent downflow contactor reactor (CDCR)[J] . Idoko J. Ochuma,Robert P. Fishwick,Joseph Wood,J. Mike Winterbottom.Journal of Hazardous Materials . 2007 (3)
  • [5] In situ electron microscopy investigation of Fe(III)-doped TiO2 nanoparticles in an aqueous environment
    Wang, CY
    Böttcher, C
    Bahnemann, DW
    Dohrmann, JK
    [J]. JOURNAL OF NANOPARTICLE RESEARCH, 2004, 6 (01) : 119 - 122
  • [6] Properties and morphology of CdS compounded TiO 2 visible-light photocatalytic nanofilms coated on glass surface[J] . Wang Chengyu,Shang Huamei,Tao Ying,Yuan Tongsuo,Zhang Guowu.Separation and Purification Technology . 2003 (1)
  • [7] The Preparation, Characterization, and their Photocatalytic Activities of Rare-Earth-Doped TiO 2 Nanoparticles[J] . An-Wu Xu,Yuan Gao,Han-Qin Liu.Journal of Catalysis . 2002 (2)
  • [8] Ordered mesoporous and microporous molecular sieves functionalized with transition metal complexes as catalysts for selective organic transformations. De Vos D E,Dams M,Sels B F,Jacobs P A. Chemical Reviews . 2002