Experimental investigation on phase equilibria of Ce-Sn-Zn system at 400 ℃

被引:1
作者
梁建烈 [1 ,2 ,3 ]
韩艳美 [1 ,2 ]
欧阳义芳 [2 ]
谢世标 [1 ]
蒙洁丽 [1 ]
朱立炫 [1 ]
零妙然 [1 ,2 ]
机构
[1] Institute of Materials Science, College of Science, Guangxi University for Nationalities
[2] Department of Physics, Guangxi University
[3] Guangxi Key Laboratory of Hybrid Computational and IC Design Analysis
关键词
phase diagram; Ce-Sn-Zn; rare earths;
D O I
暂无
中图分类号
TG131 [合金学理论];
学科分类号
080502 ;
摘要
The Ce-Sn-Zn alloys were prepared by furnace melting. The isothermal section of the Ce-Sn-Zn system at 400 oC over the whole composition range was established by using X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS). A new ternary compound, CeSn 2 Zn 2 , was discovered in the present work. This compound adopted CaBe 2 Ge 2 structure type (space group P4/nmm) with the lattice parameters of a=0.4455 (9) nm and c=1.0348 (1) nm. The existence of previously known ternary compounds, CeSnZn and Ce 2 SnZn 3 , were confirmed, too. The maximum solubility of Zn in CeSn 3 was determined to be 12.7 at.%.
引用
收藏
页码:916 / 922
页数:7
相关论文
共 10 条
  • [1] Effects of cerium on Sn-Ag-Cu alloys based on finite element simulation and experiments[J]. 张亮,薛松柏,陈燕,韩宗杰,王俭辛,禹胜林,卢方焱. Journal of Rare Earths. 2009(01)
  • [2] Development of Sn–Zn lead-free solders bearing alloying elements[J] . Liang Zhang,Song-bai Xue,Li-li Gao,Zhong Sheng,Huan Ye,Zheng-xiang Xiao,Guang Zeng,Yan Chen,Sheng-lin Yu. Journal of Materials Science: Materials in Electr . 2010 (1)
  • [3] Effects of rare earths on properties and microstructures of lead-free solder alloys
    Zhang, Liang
    Xue, Song-bai
    Gao, Li-li
    Zeng, Guang
    Sheng, Zhong
    Chen, Yan
    Yu, Sheng-lin
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2009, 20 (08) : 685 - 694
  • [4] Microstructure and mechanical behavior of novel rare earth-containing Pb-free solders
    Dudek, M. A.
    Sidhu, R. S.
    Chawla, N.
    Renavikar, M.
    [J]. JOURNAL OF ELECTRONIC MATERIALS, 2006, 35 (12) : 2088 - 2097
  • [5] The wettability and microstructure of Sn-Zn-RE alloys
    Wu, CML
    Law, CMT
    Yu, DQ
    Wang, L
    [J]. JOURNAL OF ELECTRONIC MATERIALS, 2003, 32 (02) : 63 - 69
  • [6] The properties of Sn-9Zn lead-free solder alloys doped with trace rare earth elements
    Wu, CML
    Yu, DQ
    Law, CMT
    Wang, L
    [J]. JOURNAL OF ELECTRONIC MATERIALS, 2002, 31 (09) : 921 - 927
  • [7] POWDER CELL – a program for the representation and manipulation of crystal structures and calculation of the resulting X‐ray powder patterns[J] . W. Kraus,G. Nolze. J. Appl. Cryst. . 1996 (3)
  • [8] On RZn 1.5 X 0.5 intermetallic compounds (R = rare earth, X = germanium, tin)[J] . D. Rossi,R. Ferro. Journal of Alloys and Compounds . 1996 (1)
  • [9] The phase diagram of the Ce-Sn System up to 50 AT.% Sn[J] . E. A. Franceschi,G. A. Costa. Journal of Thermal Analysis . 1988 (2)
  • [10] Crystal structures of the compounds Ce 3 Zn 22 , La 3 Zn 22 , and Pr 3 Zn 22[J] . P. I. Kripyakevich,Yu. B. Kuz’ma,N. S. Ugrin. Journal of Structural Chemistry . 1968 (4)