Tunable color emission in K3Gd(PO4)2:Tb3+,Sm3+ phosphor for n-UV white light emitting diodes

被引:5
作者
王婷 [1 ]
徐旭辉 [1 ,2 ]
周大成 [1 ,2 ]
邱建备 [1 ,2 ]
余雪 [1 ]
机构
[1] College of Materials Science and Engineering, Kunming University of Science and Technology
[2] Key Laboratory of Advanced Materials of Yunnan Province
基金
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词
phosphors; energy transfer; luminescence; tunable colors; rare earths;
D O I
暂无
中图分类号
TQ422 [光化学物质];
学科分类号
0817 ;
摘要
A series of K3Gd(PO4)2:Tb3+,Sm3+ phosphors were synthesized through solid state reaction. By co-doping Tb3+ and Sm3+into K3Gd(PO4)2 host and singly varying the doping concentration of Sm3+, tunable colors from green to yellow and then to orange were obtained in K3Gd(PO4)2:Tb3+,Sm3+ phosphors under the excitation at 373 nm. The energy transfer process from Tb3+ to Sm3+ was verified through luminescence spectra and fluorescence decay curves. Moreover, the energy transfer mechanism was demonstrated to be the quadrupole-quadrupole interaction. The results indicated that K3Gd(PO4)2:Tb3+,Sm3+ phosphors could be a potential application for n-UV white light emitting diodes.
引用
收藏
页码:361 / 365
页数:5
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