Direct growth of plasmonic nanorod forests on paper substrates for low-cost flexible 3D SERS platforms

被引：57

作者：

Araújo, Andreia ^{[1
]}

Pimentel, Ana ^{[1
]}

Oliveira, Maria João ^{[1
]}

Mendes, Manuel J. ^{[1
]}

Franco, Ricardo ^{[2
]}

Fortunato, Elvira ^{[1
]}

Águas, Hugo ^{[1
]}

Martins, Rodrigo ^{[1
]}

机构：

[1] I3N/CENIMAT, Department of Materials Science, Faculty of Sciences and Technology, UniversidadeNOVAde Lisboa, CEMOP, UNINOVA, Campus de Caparica, Caparica,2829-516, Portugal

[2] REQUIMTE, UCIBIO, Department of Chemistry, Faculty of Sciences and Technology, Universidade NOVA de Lisboa, Campus de Caparica, Caparica,2829-516, Portugal

来源：

Flexible and Printed Electronics | 2017年 / 2卷 / 01期

基金：

欧盟地平线“2020”;

关键词：

Substrates - Synthesis (chemical) - II-VI semiconductors - Metal nanoparticles - Silver nanoparticles - Thermal evaporation - Biocompatibility - Zinc oxide - Nanorods - Raman spectroscopy - Temperature - Forestry;

D O I：

10.1088/2058-8585/2/1/014001

中图分类号：

学科分类号：

摘要：

Paper substrates, coated with ZnO nanorods (NRs) decorated with Ag nanoparticles (NPs), allowed the production of inexpensive, highly-performing and extremely reproducible three-dimensional (3D) SERS platforms. The ZnO NRs were synthesized by a simple, fast and low-temperature hydrothermal method assisted by microwave radiation and made SERS-active by decorating them with a dense array of silver nanoparticles deposited via a single-step thermal evaporation technique. Using Rhodamine 6G (R6G) as a probe molecule, with an amount down to 10-9 M, the SERS substrates allowed a Raman signal enhancement of 107. The contribution of the inter-Ag-NPs gaps for 3D geometry, ZnO NRs orientation and the large sensing area allowed by theNRscaffolds, were determinant factors for the significant Raman enhancement observed. The results demonstrate that plasmonic nanorod forests, covered with Ag NPs, are efficient SERS substrates with the advantages of being recyclable, flexible, lightweight, portable, biocompatible and extremely low-cost.

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