The employment of FTIR spectroscopy and chemometrics for classification and quantification of mutton fat in cod liver oil

被引:13
作者
Rohman, Abdul [1 ,2 ]
Sunarminingsih, Retno [1 ,2 ]
Man, Y.B. Che [3 ]
机构
[1] Laboratory of Analytical Chemistry, Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Gadjah Mada University, Yogyakarta
[2] Research Center of Halal Products, Gadjah Mada University, Yogyakarta
[3] Indonesia laboratory of Analysis and Authentication, Halal Products Research Institute, Universiti Putra Malaysia, Serdang, Selangor
关键词
Cod liver oil; Discriminant analysis; Ftir spectroscopy; Multivariate calibration; Mutton fat;
D O I
10.3923/ajft.2012.151.159
中图分类号
学科分类号
摘要
In pharmaceutical field, Cod Liver Oil (CLO) is one of the potential sources of long1 chain omega-3 fatty acids and fat soluble vitamins, especially vitamin A. In the fats and oils industry, CLO has high price. As a consequence, some market players try to blind CLO with other fats and oils to gain economics profit. Animal fats like Mutton Fat (MF) are potential to be mixed with CLO due to the similarity in terms of fatty acid composition. This study focused on the application of FTIR spectroscopy in conjunction with chemometrics for classification and quantification of MF as adulterant in CLO. The combined spectral regions of 3,010-2995 and 1,500-900 cm -1 were used for classification between CLO and CLO blended with MF at various concentrations, with the aid of Discriminant Analysis (DA). DA is able to classify CLO and CLO adulterated with MF without any mistakenly grouped. These frequency regions were also used for quantification of MF in CLO, offering the highest R2 value (0.992) and the lowest root mean square error of calibration (RMSEC) value (1.31% v/v), compared with other studied spectral regions. © 2012 Academic Journals Inc.
引用
收藏
页码:151 / 159
页数:8
相关论文
共 24 条
[1]  
Official and Tentative Methods of the American Oil Chemists Society, (1996)
[2]  
Aparicio R., Aparicio-Ruiz R., Authentication of vegetable oils by chromatographic techniques, J. Chromatogr. A, 881, pp. 93-104, (2000)
[3]  
Aparicio R., Aparicio-Ruiz R., Chemometrics as an Aid in Authentication, Oils and Fats Authentication, pp. 156-180, (2002)
[4]  
Ballabio D., Todeschini R., Multivariate Classification for Qualitative Analysis, Infrared Spectroscopy for Food Quality: Analysis and Control, pp. 83-104, (2009)
[5]  
Guillen M.D., Cabo N., Characterization of edible oils and lard by fourier transform infrared spectroscopy. Relationships between composition and frequency of concrete bands in the fingerprint region, J. Am. Oil Chem. Soc., 74, pp. 1281-1286, (1997)
[6]  
Gunstone F.D., The Chemistry of Oils and Fats: Sources, Composition, Properties and Uses, (2004)
[7]  
Jude S., Roger S., Martel E., Besson P., Richard S., Et al., Dietary long-chain &omega
[8]  
-3 fatty acids of marine origin: A comparison of their protective effects on coronary heart disease and breast cancers, Prog. Biophys. Mol. Biol., 90, pp. 299-325, (2006)
[9]  
Kaur S., Das M., Functional foods: An overview, Food Sci. Biotechnol., 20, pp. 861-875, (2011)
[10]  
Lerma-Garcia M.J., Ramis-Ramos G., Herrero-Martinez J.M., Simo-Alfonso E.F., Authentication of extra virgin olive oils by Fourier-transform infrared spectroscopy, Food Chem, 118, pp. 78-83, (2010)