Synthesis and Crystal Structures of (C4H12N2)[Mn(HSeO3)2Cl2] and [(C4N12N2)2Br]2[Mn(HSeO3)2Br2]-New Representatives of the Modular Family of "Layered Hydroselenites"

被引：0
作者：
Kireev, V. E. [1 ]
Dmitriev, D. N. [1 ,2 ]
Charkin, D. O. [1 ,2 ]
Aksenov, S. M. [1 ]
机构：
[1] Russian Acad Sci, Kola Sci Ctr, Apatity 184209, Murmansk Oblast, Russia
[2] Lomonosov Moscow State Univ, Fac Chem, Moscow 119991, Russia
来源：
CRYSTALLOGRAPHY REPORTS | 2025年 / 70卷 / 03期
基金：
俄罗斯科学基金会;
关键词：
TOPOLOGY-SYMMETRY ANALYSIS; HYDROGEN-BONDS; MAGNETIC-PROPERTIES; PHASE-TRANSITIONS; IODATE FAMILIES; POLYTYPISM; SELENITES; DESIGN; LONE;
D O I：
10.1134/S1063774525600206
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Single crystals of two new complex hydroselenites with organic cations-(C4H12N2)[Mn(HSeO3)2Cl2] (1) and [(C4N12N2)Br]2[Mn(HSeO3)2Br2] (2)-were obtained as the products of the reaction of piperazine, selenious acid, and manganese halide in an aqueous medium. The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis; they are characterized by monoclinic symmetry (1: P21/c, a = 9.7557(7) & Aring;, b = 7.3930(5) & Aring;, c = 9.7660(6) & Aring;, beta = 116.839(7)degrees; 2: P21/c, a = 14.4093(3) & Aring;, b = 7.3822(1) & Aring;, c = 10.3051(3) & Aring;, beta = 101.553(2)degrees). The crystal structures of both compounds are constructed by alternating layers of the composition [Mn(HSeO3)2X2]2- (X = Cl, Br) and layers formed by piperazinium cations. Compound 1 is a structural analogue of the previously described compound (C4H12N2)[Cd(HSeO3)2Cl2], while the crystal structure of compound 2 belongs to a new structural type, is characterized by a modular structure, and contains layers including both piperazinium cations and bromine anions.
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页码：433 / 440
页数：8
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