Microstructure, short-term and long-term leaching behaviour of zinc encapsulated by calcium carbide residue-fly ash

被引：0

作者：

Somna K. ^{[1
]}

Jaturapitakkul C. ^{[2
]}

Kajitvichyanukul P. ^{[3
,4
]}

机构：

[1] Department of Environmental Engineering, Faculty of Engineering, King Mongkut's University of Technology, Thonburi, 10140, Bangkok

[2] Department of Civil Engineering, Faculty of Engineering, King Mongkut's University of Technology, Thonburi, 10140, Bangkok

[3] Department of Environmental Engineering, Faculty of Engineering, Center of Excellence for Environmental and Hazardous Waste Management, King Mongkut's University of Technology, Thonburi, 10140, Bangkok

[4] Department of Civil Engineering, Faculty of Engineering, Naresuan University, Phitsanulok

来源：

International Journal of Environment and Waste Management | 2016年 / 17卷 / 01期

关键词：

Cement; Immobilisation; Leaching; Waste; Zinc;

D O I：

10.1504/IJEWM.2016.076424

中图分类号：

学科分类号：

摘要：

This study evaluates the use of a calcium carbide residue-fly ash mixture as a new material to encapsulate zinc. Zinc was added into both calcium carbide residue-fly ash pastes (ZnCF) and ordinary Portland cement (ZnOPC) for comparison purposes. The fracture surfaces, crystalline phases, and zinc leaching behaviours of pastes were determined. A new crystalline phase of calcium zincate (Ca(Zn2(OH)6).2H2O) was detected. The compressive strengths of ZnCF pastes were dramatically decreased, whereas the strengths of the ZnOPC pastes were slightly decreased. However, the compressive strengths of the ZnCF pastes after curing for 28 days were comparable to those of solidification cements used for hazardous waste disposal in secured landfills. Evaluation of the short-term leaching behaviour showed that the zinc concentrations that leached out were much lower than the allowable limit (500 mg/L). The diffusion coefficient (De) and leachability index (LX) for long-term leaching of samples were not significantly different. Copyright © 2016 Inderscience Enterprises Ltd.

引用

页码：26 / 43

页数：17

共 26 条

[21]

Ribe V., Nehrenhein E., Odlare M., Waara S., Leaching of contaminants from untreated pine bark in a batch study: Chemical analysis and ecotoxicological evaluation, J. Hazard. Mater., 163, 2-3, pp. 1096-1100, (2009)

[22]

Salihoglu G., Pinarli V., Steel foundry electric arc furnace dust management: Stabilization by using lime and Portland cement, J Hazard. Mater., 153, 3, pp. 1110-1116, (2008)

[23]

Salihoglu G., Pinarli V., Salihoglu N.K., Karaca G., Properties of steel foundry electric arc furnace dust solidified/stabilized with Portland cement, J. Environ. Manage., 85, 1, pp. 190-197, (2007)

[24]

Srivastava S., Chaudhary R., Khale D., Influence of pH, curing time and environmental stress on the immobilization of hazardous waste using activated fly ash, J. Hazard. Mater., 153, 3, pp. 1103-1109, (2008)

[25]

Stephan D., Maleki H., Knofel D., Eber B., Hardtl R., Influence of Cr, Ni and Zn on the properties of pure clinker phases Part II. C3A and C4AF, Cem. Concr. Res., 29, 5, pp. 651-657, (1999)

[26]

Stephan D., Maleki H., Knofel D., Eber B., Hardtl R., Influence of Cr, Ni and Zn on the properties of pure clinker phases Part I. C3S, Cem. Concr. Res., 29, 4, pp. 545-552, (1999)

← 1 2 3 →