Preparation of fluorescent mesoporous silica nanoparticles and their properties

被引:0
作者
Yang D. [1 ]
Wang Y. [1 ]
机构
[1] School of Materials Science and Engineering, Wuhan University of Technology, Wuhan
来源
Cailiao Daobao/Materials Review | 2016年 / 30卷 / 04期
关键词
Fluorescent dyes; Mesoporous silica; Organic/inorganic composite fluorescent material; Sol-gel method;
D O I
10.11896/j.issn.1005-023X.2016.08.004
中图分类号
学科分类号
摘要
Using single hexadecyl trimethyl ammonium bromide (CTAB) surfactant coat dye and transfer it into the water, and preparing fluorescent dye for nuclear, mesoporous silica nanoparticles (MSNs) for shell of fluorescent mesoporous silica nanoparticles by sol-gel method. DLS was used to study the influence of tetraethyl orthosilicate, surfactant, ammonia, dye concentration on the particle size, using SEM, TEM, TG, UV and PL spectra characterize and discusses composite nanoparticles structure, morphology, thermal stability and optical. The results show that with the increase of the tetraethyl orthosilicate and ammonia, the particle size increases; the particle size will be larger when in large amount surfactant; its size will be less affected at lower dye concentrations. The preparation of the particle can be controlled around 100 nm; Fluorescence intensity increase and the optimal doping mass ratio of dye and silicon dio-xide is 1.5×10-3; thermal stability improve limited due to the physical coat and ultraviolet aging resistance is significantly improved. © 2016, Materials Review Magazine. All right reserved.
引用
收藏
页码:18 / 23
页数:5
相关论文
共 22 条
[11]  
Hench L.L., West J.K., The sol-gel process, Chem Rev, 90, 1, (1990)
[12]  
Jiang H., Wang X., Zhong F., Et al., Preparation and characterization of monodisperse nano-silica spherical, Mater Rev, 24, (2010)
[13]  
Bourgeat-Lami E., Insulaire M., Reculusa S., Et al., Nucleation of polystyrene latex particles in the presence of gamma-methacryloxypropyl-trimethoxysilane: Functionalized silica particles, J Nanosci Nanotechnol, 6, 2, (2006)
[14]  
Vartuli J., Shih S., Kresge C., Et al., Potential applications for M41S type mesoporous molecular sieves, Studies Surf Sci Catal, 117, 98, (1998)
[15]  
Fan H.Y., Nanocrystal-micelle: Synthesis self-assembly and application, Chem Commun, 7345, 12, (2008)
[16]  
Zanetti-Ramos B.G., Fritzen-Garcia M.B., Creczynski-Pasa T.B., Et al., Characterization of polymeric particles with electron microscopy, dynamic light scattering, and atomic force microscopy, Particulate Sci Technol, 28, 5, (2001)
[17]  
Zhao D., Qin W.P., Zhang J.S., Et al., Blue-shifted luminescence from the rhodamine 6G incorporated in mesoporous MCM-41, J Luminescence, 24, 6, (2003)
[18]  
Nagao D., Anzai N., Kobayashi Y., Et al., Preparation of highly monodisperse poly(methyl methacrylate) particles incorporating fluorescent rhodamine 6G for colloidal crystals, Colloid Interf Sci, 298, 1, (2006)
[19]  
Yang F., Rong J., Liu Y., Et al., Research on the Rhodamine 6G doped mesoporous silica, J Funct Mater, 36, 4, (2005)
[20]  
Qian G., Wang M., Study on concentration quenching mechanism of organic luminous material in SiO<sub>2</sub> glass gel, J Funct Mater, 3, 3, (1998)