Real-Time Gas Identification at Room Temperature Using UV-Modulated Sb-Doped SnO2 Sensors via Machine Learning

被引:0
作者
Lin, Yan-Fong [1 ]
Chi, Yu-Chen [1 ]
Tseng, Sheng-Hong [2 ]
Wang, Te-Fu [2 ]
Lin, Ying-Tsung [2 ]
Yang, Min-Ta [2 ]
Lin, Chih-Hao [2 ]
Liao, Su-Yu [2 ]
Huang, Chun-Ying [2 ]
机构
[1] Natl Taiwan Univ, Dept Engn Sci & Ocean Engn, Photon Grp, Taipei 10660, Taiwan
[2] Natl Chi Nan Univ, Dept Appl Mat & Optoelect Engn, Nantou 54561, Taiwan
关键词
Sb-doped SnO2; machine learning; selectivity; UV-modulated; optical fingerprint; P-TYPE; ARRAY; NO2; OXIDE; H-2; CO;
D O I
10.1021/acssensors.5c01183
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This study presents a novel approach for real-time gas identification at room temperature. We use UV-modulated Sb-doped SnO2 sensors combined with machine learning. Our method exclusively employs the gas response (R) as the sole metric. This eliminates the need for time-dependent parameters such as response and recovery times. By modulating the UV light intensity at five distinct levels (5, 10, 15, 20, and 30 mW/cm(2)), we generate a five-dimensional optical fingerprint. This fingerprint captures subtle variations in sensor response under different illumination conditions. Gas discrimination was evaluated for both oxidizing gases (O-3 and NO2) and reducing gases (NH3 and H-2). Our machine learning results show that Support Vector Machine (SVM) and K-Nearest Neighbors (KNN) achieve nearly 100% accuracy when four UV intensity levels are used. Using R as the sole input metric allows for instantaneous response detection, which is essential for real-time gas identification. This approach addresses the limitations of conventional thermally activated sensors that require multiple parameters and paves the way for the development of rapid-response monitoring systems.
引用
收藏
页码:5129 / 5139
页数:11
相关论文
共 43 条
[1]   Selective identification and quantification of VOCs using metal nanoparticles decorated SnO2 hollow-spheres based sensor array and machine learning [J].
Acharyya, Snehanjan ;
Bhowmick, Plaban Kumar ;
Guha, Prasanta Kumar .
JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 968
[2]   Single resistive sensor for selective detection of multiple VOCs employing SnO2 hollowspheres and machine learning algorithm: A proof of concept [J].
Acharyya, Snehanjan ;
Jana, Biswabandhu ;
Nag, Sudip ;
Saha, Goutam ;
Guha, Prasanta Kumar .
SENSORS AND ACTUATORS B-CHEMICAL, 2020, 321
[3]   Structural and optical characteristics of Sb doped SnO2 nanoparticles and their boosted photocatalytic activity under visible light irradiation [J].
Ahmad, Towseef ;
Ansari, Mohd Zubair .
CERAMICS INTERNATIONAL, 2023, 49 (22) :35740-35756
[4]   Adsorption of O2, H2, CO, NH3, and NO2 on ZnO nanotube:: A density functional theory study [J].
An, Wei ;
Wu, Xiaojun ;
Zeng, X. C. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (15) :5747-5755
[5]   Detection of ammonia gas at room temperature through Sb doped SnO2 thin films: Improvement in sensing performance of SnO2 [J].
Boomashri, M. ;
Perumal, P. ;
Gunavathy, K. V. ;
Alkallas, Fatemah H. ;
Trabelsi, Amira Ben Gouider ;
Shkir, Mohd ;
AlFaify, S. .
CERAMICS INTERNATIONAL, 2023, 49 (06) :10096-10106
[6]   An optimised gas sensor microsystem for accurate and real-time measurement of nitrogen dioxide at ppb level [J].
Brunet, J. ;
Garcia, V. Parra ;
Pauly, A. ;
Varenne, C. ;
Lauron, B. .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 134 (02) :632-639
[7]  
Chen KL, 2015, Analytical Chemistry Research, V4, P8, DOI 10.1016/j.ancr.2015.03.001
[8]   Investigation on Sensing Performance of Highly Doped Sb/SnO2 [J].
Feng, Zhifu ;
Gaiardo, Andrea ;
Valt, Matteo ;
Fabbri, Barbara ;
Casotti, Davide ;
Krik, Soufiane ;
Vanzetti, Lia ;
Della Ciana, Michele ;
Fioravanti, Simona ;
Caramori, Stefano ;
Rota, Alberto ;
Guidi, Vincenzo .
SENSORS, 2022, 22 (03)
[9]   Structural, morphological and electronic study of CVD SnO2:Sb films [J].
Haireche, S. ;
Boumeddiene, A. ;
Guittoum, A. ;
El Hdiy, A. ;
Boufelfel, A. .
MATERIALS CHEMISTRY AND PHYSICS, 2013, 139 (2-3) :871-876
[10]   Advances in metal oxide semiconductor gas sensor arrays based on machine learning algorithms [J].
Han, Jiayue ;
Li, Huizi ;
Cheng, Jiangong ;
Ma, Xiang ;
Fu, Yanyan .
JOURNAL OF MATERIALS CHEMISTRY C, 2025, 13 (09) :4285-4303