Electrochemical investigation of corrosion behavior of 304 and 316L stainless steels in high-temperature water

被引:0
作者
Duan Z. [1 ]
Du D. [1 ]
Zhang L. [1 ]
Meng F. [2 ]
Shi X. [2 ]
机构
[1] School of Nuclear Science and Engineering, Shanghai Jiaotong University, Shanghai
[2] Shanghai Nuclear Engineering Research and Design Institute, Shanghai
来源
Shanghai Jiaotong Daxue Xuebao/Journal of Shanghai Jiaotong University | 2016年 / 50卷 / 02期
关键词
Corrosion behavior; Electrochemistry behavior; High-temperature; Pressured water reactor (PWR); Stainless steel;
D O I
10.16183/j.cnki.jsjtu.2016.02.010
中图分类号
学科分类号
摘要
The effects of temperature and dissolved oxygen (DO) on electrochemical behaviors and the oxide films formed on type 304 and 316L stainless steels in primary water in simulated pressured water reactor (PWR) were investigated by means of potentiodynamic polarization measurements, scanning electron microscope (SEM) observation and energy dispersive X-ray spectrum (EDS). The results revealled that the passivity of the oxide films degraded with increasing solution temperature. The corrosion potential (Ecorr) shifted to positive direction while corrosion current density (Jcorr) decreased significantly with the increase of DO. The oxide films formed on 304 and 316L stainless steels showed a double-layer characteristic, and the size of oxide particles and the space between oxide particles on outer layer increased with increasing temperature but decreased with increasing DO. The type 316L stainless steels exhibited superior corrosion resistant characteristics than 304 SS in all investigated conditions. © 2016, Editorial Board of Journal of Shanghai Jiao Tong University. All right reserved.
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页码:215 / 221
页数:6
相关论文
共 16 条
[1]  
Bosch R.W., Feron D., Celis J.P., Electrochemistry in Light Water Reactors: Reference Electrodes, Measurement, Corrosion and Tribocorrosion Issues, (2007)
[2]  
Wildgoose G.G., Giovanelli D., Lawrence N.S., Et al., High-temperature electrochemistry: A review, Electroanalysis, 16, 6, pp. 421-433, (2004)
[3]  
Han E., Wang J., Wu X., Et al., Corrosion mechanisms echanisms of stainless steel and nickel base alloys in high temperature high pressure water, Acta Metallurgica Sinica, 46, 11, pp. 1379-1390, (2010)
[4]  
Greeley R.S., Smith W.T., Stoughton R.W., Et al., Electromotive force studies in aqueous solutions at elevated temperatures. I. The standard potential of the silver chloride electrode1, Journal of Physical Chemistry, 64, 5, pp. 652-657, (1960)
[5]  
Ziemniak S.E., Hanson M., Corrosion behavior of NiCrMo alloy 625 in high temperature, hydrogenated water, Corrosion Science, 45, 7, pp. 1595-1618, (2003)
[6]  
Ziemniak S.E., Hanson M., Corrosion behavior of NiCrFe alloy 600 in high temperature, hydrogenated water, Corrosion Science, 48, 2, pp. 498-521, (2006)
[7]  
Ziemniak S.E., Hanson M., Sander P.C., Electropolishing effects on corrosion behavior of 304 stainless steel in high temperature, hydrogenated water, Corrosion Science, 50, 9, pp. 2465-2477, (2008)
[8]  
Sun H., Wu X., Han E.H., Effects of temperature on the protective property, structure and composition of the oxide film on alloy 625, Corrosion Science, 51, 11, pp. 2565-2572, (2009)
[9]  
Sun H., Wu X., Han E.H., Et al., Effects of pH and dissolved oxygen on electrochemical behavior and oxide films of 304SS in borated and lithiated high temperature water, Corrosion Science, 59, pp. 334-342, (2012)
[10]  
Huang J., Wu X., Han E.H., Electrochemical properties and growth mechanism of passive films on alloy 690 in high-temperature alkaline environments, Corrosion Science, 52, 10, pp. 3444-3452, (2010)