Synthesis and Properties of 6⁃Amino⁃4⁃（trinitromethyl）⁃2⁃carbonyl⁃1H⁃1，3，5⁃triazine

被引：0
作者：
Zhang, Tong-Wei [1 ]
Xu, Yuan-Gang [1 ]
Lu, Ming [1 ]
机构：
[1] School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing
来源：
Hanneng Cailiao/Chinese Journal of Energetic Materials | 2025年 / 33卷 / 05期
基金：
中国国家自然科学基金;
关键词：
crystal structures; detonation performance; high energy density material; synthesis; triazine derivative;
D O I：
10.11943/CJEM2024239
中图分类号：
学科分类号：
摘要：
A novel high-energy compound，6-Amino-4- （trinitromethyl）-2-carbonyl-1H-1，3，5-triazine，was synthesized in one step. The crystal structure of this compound was characterized by X-ray single crystal diffraction. Its structure and properties were characterized by 1H and 13C NMR，FT-IR and DSC. The detonation performance was calculated by EXPLO5. The sensitivity testing was performed according to the BAM standard method. The compound crystallizes in orthorhombic space group C 2/c，a=10.183（4）Å，b=9.388（3）Å，c=21.324（8）Å，V=2005.9（13）Å3，α=90°，β=100.246（10）°，γ=90°，Z=8. The calculated detonation velocity and pressure for compound 1 are 8167 m·s-1 and 27.6 GPa，respectively，with measured impact sensitivity of 6 J and friction sensitivity of 210 N. © 2025 Institute of Chemical Materials, China Academy of Engineering Physics. All rights reserved.
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页码：448 / 454
页数：6
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