Photoinduced Nickel-Catalyzed Reductive Heck Reaction

被引：0

作者：

Liu, Junjie ^{[1
]}

Zhao, Hongping ^{[1
]}

Hu, Yuanyuan ^{[1
]}

Wang, Hengxin ^{[1
]}

Yuan, Weiming ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2025年 / 45卷 / 05期

基金：

中国国家自然科学基金;

关键词：

nickel; reductive Heck reaction; visible light; organic reductant; alkene;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient visible-light induced nickel-catalyzed reductive Heck reaction of alkenes by using mild organic reductant Hantzsch ester (HEH) instead of traditional metal reductants or hydride reagents was developed. The reductive hydroarylation of acrylates with aryl halides was successfully achieved without requiring exogenous photoredox catalysts. This reaction is highlighted by the simple and mild conditions, good functional group tolerance, thus providing a complementary approach for alkenes reductive Heck reaction.

引用

页数：7