Sustainable and efficient photocatalytic tandem reaction system for H2O2 production simultaneous bleaching of fabric over K-doped g-C3N4

被引:0
作者
Cui, Qingyun [1 ]
Li, Chen [2 ]
Yang, Wenxiu [1 ]
Liu, Jiayin [1 ]
Wang, Wei [3 ]
Hu, Xuemin [1 ]
Lu, Yuanyuan [4 ]
Wang, Shuo [1 ]
机构
[1] Hebei Univ Sci & Technol, Coll Text & Garments, Innovat Ctr Text & Garment Technol, Shijiazhuang 050018, Hebei, Peoples R China
[2] Beijing Inst Technol, Sch Phys & Optoelect Engn, Beijing 100048, Peoples R China
[3] Suzhou Univ Technol, Dept Text & Garment Engn, Suzhou 215500, Peoples R China
[4] Zhejiang Sci Tech Univ, Coll Text Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China
关键词
Green fabric bleaching; Photocatalytic; Synchronization mechanism; GRAPHITIC CARBON NITRIDE; HYDROGEN-PEROXIDE;
D O I
10.1016/j.colsurfa.2025.137640
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The primary aim of this study was to devise an efficient and environmentally eco-friendly alternative technology to traditional hydrogen peroxide (H2O2) fabric bleaching, while also introducing a novel bleaching mechanism. Initially, K-doped g-C3N4 was synthesized and subsequently employed in a photocatalytic bleaching fabric system based on H2O2 ready-to-use process. Results revealed that the impressive fabric whiteness values were achieved with an obvious reduced additives and lower temperatures contrasted with traditional H2O2 bleaching methods. And the K doping content played pivotal role in influencing H2O2 yields and fabric whiteness. Remarkably, unlike the degradation of free mulberry, the removal on cotton fabrics shows an induction period.& sdot;O2-and H2O2 were found as primary species responsible for fabric whitening, rather than active ingredients derived from H2O2 decomposition, which differs from conventional bleaching mechanism. Consequently, this study offers a fresh perspective on the promising path towards green and efficient fabric bleaching method, ultimately contributing to a cleaner production in the printing and dyeing industry.
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页数:10
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