Smart-responsive chitosan-based materials for precise degradation control and environmental remediation: A review

被引：1
作者：
Zhang, Xiaoliang [1 ]
Wu, Sijia [1 ]
Liu, Ran [1 ]
Jiang, Haoran [1 ]
Jing, Shubo [2 ]
Zhuang, Hong [1 ]
机构：
[1] Jilin Univ, Coll Food Sci & Engn, Changchun 130062, Jilin, Peoples R China
[2] Jilin Univ, Coll Mat Sci & Engn, Changchun 130062, Jilin, Peoples R China
来源：
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES | 2025年 / 319卷
关键词：
Chitosan-based materials; Environmental remediation; SRCMs; CROSS-LINKED CHITOSAN; HEAVY-METAL IONS; QUINONE OXIDATION; IN-VITRO; REMOVAL; ADSORPTION; PH; DERIVATIVES; WATER; IMMOBILIZATION;
D O I：
10.1016/j.ijbiomac.2025.144982
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Smart-responsive chitosan-based materials (SRCMs) exhibit multi-stimuli reactivity, biodegradability, and environmental compatibility, making them promising candidates for sustainable environmental remediation. This review summarizes the latest progress in the molecular design of SRCMs, including the integration of pH, temperature, light, enzyme, and redox-responsive moieties for precise degradation control. Emphasis is placed on novel degradation mechanisms such as triggered depolymerization and cascade mineralization, alongside multifunctional applications in pollutant adsorption, heavy metal immobilization, and smart packaging. Future perspectives on AI-driven material design and in-situ monitoring systems are also discussed, highlighting the strategic role of SRCMs in carbon neutrality and the circular economy.
引用
收藏
页数：14
相关论文
共 175 条
[1]   Gelatin and Chitosan as Meat By-Products and Their Recent Applications [J].
Abd Elgadir, M. ;
Mariod, Abdalbasit Adam .
FOODS, 2023, 12 (01)
[2]   Biodegradable redox sensitive chitosan based microgels for potential agriculture application [J].
Agrawal, Garima ;
Dhiman, Ankita ;
Bhardwaj, Dimpy ;
Goswami, Kajal .
CARBOHYDRATE POLYMERS, 2023, 313
[3]   Preparation of Chitosan-Carbon Nanotubes Decorated with ZnO@laccase: Application in the Removal of Bisphenol A from Aqueous Solution [J].
Ahari, Shabnam Maali ;
Tabatabaei, Zohreh Ghazi .
JOURNAL OF ENVIRONMENTAL ENGINEERING, 2023, 149 (02)
[4]   Sharp Hydrophilicity Switching and Conformality on Nanostructured Surfaces Prepared via Initiated Chemical Vapor Deposition (iCVD) of a Novel Thermally Responsive Copolymer [J].
Alf, Mahriah E. ;
Godfrin, Paul D. ;
Hatton, T. Alan ;
Gleason, Karen K. .
MACROMOLECULAR RAPID COMMUNICATIONS, 2010, 31 (24) :2166-2172
[5]   Chitosan based metal-chelated copolymer nanoparticles: Laccase immobilization and phenol degradation studies [J].
Alver, Erol ;
Metin, Aysegul Ulku .
INTERNATIONAL BIODETERIORATION & BIODEGRADATION, 2017, 125 :235-242
[6]   Natural carbohydrate-based thermosensitive chitosan/pectin adsorbent for removal of Pb(II) from aqueous solutions [J].
Araujo, Lucas Del Coli B. ;
de Matos, Henrique K. ;
Facchi, Debora P. ;
de Almeida, Debora A. ;
Goncalves, Bruna M. G. ;
Monteiro, Johny P. ;
Martins, Alessandro F. ;
Bonafe, Elton G. .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2021, 193 :1813-1822
[7]   Silica@poly(chitosan-N-isopropylacrylamide-methacrylic acid) microgels: Extraction of palladium (II) ions and in situ formation of palladium nanoparticles for pollutant reduction [J].
Arif, Muhammad ;
Raza, Hamid ;
Haroon, Shah M. ;
Ben Moussa, Sana ;
Tahir, Fatima ;
Alzahrani, Abdullah Yahya Abdullah .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2024, 270
[8]   Chitosan-based materials for heavy metal adsorption: Recent advancements, challenges and limitations [J].
Ashraf, Asma ;
Dutta, Joydeep ;
Farooq, Aiman ;
Rafatullah, Mohd. ;
Pal, Kaushik ;
Kyzas, George Z. .
JOURNAL OF MOLECULAR STRUCTURE, 2024, 1309
[9]   Synthesis and Characterization of Thermoresponsive Chitosan-graft-poly(N-isopropylacrylamide) Copolymers [J].
Babelyte, Migle ;
Peciulyte, Laura ;
Navikaite-Snipaitiene, Vesta ;
Bendoraitiene, Joana ;
Samaryk, Volodymyr ;
Rutkaite, Ramune .
POLYMERS, 2023, 15 (15)
[10]   Chitosan as an environment friendly biomaterial - a review on recent modifications and applications [J].
Bakshi, Prasanna S. ;
Selvakumar, D. ;
Kadirvelu, K. ;
Kumar, N. S. .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2020, 150 :1072-1083
12345678910