Dual AIE and Visible-Light-Driven Photoswitchable Polymer for Super-resolution Imaging

被引：0

作者：

Yu, Hongbo ^{[1
]}

Li, Ruiyao ^{[1
]}

Wu, Mei ^{[2
]}

Huang, Chengxin ^{[1
]}

Hou, Shuai ^{[1
]}

Zhou, Qinghai ^{[1
]}

Zhu, Feng-Yu ^{[2
]}

Xiao, Fan ^{[1
]}

Zhu, Dongyuan ^{[1
]}

Zhu, Ming-Qiang ^{[2
]}

Li, Chong ^{[2
]}

Xu, Jingjing ^{[1
]}

Xiao, Shengxiong ^{[1
]}

机构：

[1] Shanghai Normal Univ, Coll Chem & Mat Sci, Shanghai Frontiers Sci Ctr Biomimet Catalysis, Shanghai Key Lab Rare Earth Funct Mat,Educ Minist,, Shanghai 200234, Peoples R China

[2] Huazhong Univ Sci & Technol, Sch Opt & Elect Informat, Wuhan Natl Lab Optoelect WNLO, Wuhan 430074, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2025年 / 17卷 / 17期

基金：

上海市自然科学基金;

关键词：

diarylethene; aggregation-induced emission; photoresponsive polymer; super-resolution imaging; tetraphenylethylene; AGGREGATION-INDUCED EMISSION; DITHIENYLETHENE; FLUORESCENCE; EXCITATION; MOLECULES; ENERGY; MEMORY;

D O I：

暂无

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Photochromic polymers and aggregation-induced emission (AIE) materials show great potential for many applications. To explore the synergy of both characteristics in polymer material areas, we reported the first synthesis of tetraphenylethylene (TPE)-diarylethene (DAE) polymer and its application as a super-resolution probe for imaging self-assembled cylindrical micelles of PSt38k-b-PEO11k. The polymer exhibits high fluorescence ON/OFF ratios, visible-light-driven photocycloreversion, and AIE properties. Compared with other DAE materials studied in super-resolution imaging, our polymer shows advantages of visible-light-driven photocycloreversion, higher resolution, higher fluorescence quantum yield, or higher thermal stability.

引用

页码：25801 / 25809

页数：9

共 49 条

[1] Stimuli-chromism of photoswitches in smart polymers: Recent advances and applications as chemosensors [J].

Abdollahi, Amin ;

Roghani-Mamaqani, Hossein ;

Razavi, Bahareh .

PROGRESS IN POLYMER SCIENCE, 2019, 98

[2] Construction of Mechanically Interlocked Fluorescence Photoswitchable [2]Rotaxane with Aggregation-Induced Emission and Molecular Shuttling Behaviors [J].

Alene, Dagninet Yeshiwas ;

Srinivasadesikan, Venkatesan ;

Lin, Ming-Chang ;

Chung, Wen-Sheng .

JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (09) :5530-5542

[3] One-colour control of activation, excitation and deactivation of a fluorescent diarylethene derivative in super-resolution microscopy [J].

Arai, Yuhei ;

Ito, Syoji ;

Fujita, Hajime ;

Yoneda, Yusuke ;

Kaji, Takahiro ;

Takei, Satoshi ;

Kashihara, Ryota ;

Morimoto, Masakazu ;

Irie, Masahiro ;

Miyasaka, Hiroshi .

CHEMICAL COMMUNICATIONS, 2017, 53 (29) :4066-4069

[4] Advances in photonics of organic photochromism [J].

Barachevsky, V. A. .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2018, 354 :61-69

[5] Designing Molecular Photoswitches for Soft Materials Applications [J].

Boelke, Jan ;

Hecht, Stefan .

ADVANCED OPTICAL MATERIALS, 2019, 7 (16)

[6] The Role of Morphology in Optically Switchable Transistors Based on a Photochromic Molecule/p-Type Polymer Semiconductor Blend [J].

Carroli, Marco ;

Duong, Duc T. ;

Buchaca-Domingo, Ester ;

Liscio, Andrea ;

Borjesson, Karl ;

Herder, Martin ;

Palermo, Vincenzo ;

Hecht, Stefan ;

Stingelin, Natalie ;

Salleo, Alberto ;

Orgiu, Emanuele ;

Samori, Paolo .

ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (20)

[7] Macrocycles and cages based on tetraphenylethylene with aggregation-induced emission effect [J].

Feng, Hai-Tao ;

Yuan, Ying-Xue ;

Xiong, Jia-Bin ;

Zheng, Yan-Song ;

Tang, Ben Zhong .

CHEMICAL SOCIETY REVIEWS, 2018, 47 (19) :7452-7476

[8] Photoswitchable organic field-effect transistors and memory elements comprising an interfacial photochromic layer [J].

Frolova, Lyubov A. ;

Troshin, Pavel A. ;

Susarova, Diana K. ;

Kulikov, Alexander V. ;

Sanina, Nataliya A. ;

Aldoshin, Sergey M. .

CHEMICAL COMMUNICATIONS, 2015, 51 (28) :6130-6132

[9] Single-Molecule Fluorescence Photoswitching of a Diarylethene-Perylenebisimide Dyad: Non-destructive Fluorescence Readout [J].

Fukaminato, Tuyoshi ;

Doi, Takao ;

Tamaoki, Nobuyuki ;

Okuno, Katsuki ;

Ishibashi, Yukihide ;

Miyasaka, Hiroshi ;

Irie, Masahiro .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (13) :4984-4990

[10] Dynamic photoswitching of micropatterned lasing in colloidal crystals by the photochromic reaction [J].

Furumi, Seiichi ;

Fudouzi, Hiroshi ;

Sawada, Tsutomu .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (40) :21519-21528

← 1 2 3 4 5 →