Nickel Boride Supported on Graphitic Carbon Nitride as Robust and Efficient Catalyst for Transfer Hydrogenation of Nitroarenes

被引:0
作者
Kashyap, Bharti [1 ,2 ]
Kumar, Sahil [1 ,2 ]
Sharma, Devendra [1 ,2 ]
Krishnan, Venkata [1 ,2 ]
机构
[1] Indian Inst Technol Mandi, Sch Chem Sci, Mandi 175075, Himachal Prades, India
[2] Indian Inst Technol Mandi, Adv Mat Res Ctr, Mandi 175075, Himachal Prades, India
关键词
aromatic amines; GCN; heterogeneous catalysis; hydrogenation reaction; nickel boride; SELECTIVE HYDROGENATION; EVOLUTION REACTION; NI; ELECTROCATALYSTS; REDUCTION; WATER; CO;
D O I
10.1002/cnma.202500117
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrogenation of nitroarenes to aromatic amines is an essential reaction in chemical synthesis, commonly employed in pharmaceutical and industrial applications. Typically, this transformation employs molecular hydrogen (H2) as a reducing agent, but its use comes with challenges, such as flammability, handling of high-pressure systems, sophisticated reaction setup, and so on all of which increase the costs and reduces the sustainability for large-scale operations. Catalytic transfer hydrogenation (CTH) presents a facile and simple alternative. Herein, a series of nickel boride (Ni3B) supported graphitic carbon nitride (GCN) are used as catalysts to convert aromatic nitroarenes to aromatic amines via transfer hydrogenation, using hydrazine hydrate as the hydrogen source. Among a series of different weight percentage of Ni3B on GCN catalysts, the sample with 25 wt% Ni3B, shows the highest activity in nitroarene hydrogenation. The reaction conditions are thoroughly optimized by varying various parameters, including temperature, time, catalyst loading, and hydrogen source amount. In addition, the optimized catalyst shows good recyclability and stability for four reaction cycles. These findings indicate that these catalysts offer a promising solution for robust and efficient hydrogenation in organic synthesis, with potential applications in industry.
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页数:11
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共 55 条
[1]   Transition metals as dopants on nickel borides:: Their catalytic activity effect on hydrogenation reactions [J].
Acosta, Delicia ;
Ramirez, Norma ;
Erdmann, Eleonora ;
Destefanis, Hugo ;
Gonzo, Elio .
CATALYSIS TODAY, 2008, 133 (1-4) :49-55
[2]   Hydrogenation of Azides over Copper Nanoparticle Surface Using Ammonium Formate in Water [J].
Ahammed, Sabir ;
Saha, Amit ;
Ranu, Brindaban C. .
JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (17) :7235-7239
[3]   Immobilized nickel boride nanoparticles on magnetic functionalized multi-walled carbon nanotubes: a new nanocomposite for the efficient one-pot synthesis of 1,4-benzodiazepines [J].
Aminzadeh, Farkhondeh Mohammad ;
Zeynizadeh, Behzad .
NANOSCALE ADVANCES, 2023, 5 (17) :4499-4520
[4]  
Aronsson, 1960, ARK KEMI, V16, P380
[5]   Direct amination of aryl halides with ammonia [J].
Aubin, Yoann ;
Fischmeister, Cedric ;
Thomas, Christophe M. ;
Renaud, Jean-Luc .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (11) :4130-4145
[6]   Selective Hydrogenation of Furfural to Furfuryl Alcohol in the Presence of a Recyclable Cobalt/SBA-15 Catalyst [J].
Audemar, Maite ;
Ciotonea, Carmen ;
Vigier, Karine De Oliveira ;
Royer, Sebastien ;
Ungureanu, Adrian ;
Dragoi, Brindusa ;
Dumitriu, Emil ;
Jerome, Francois .
CHEMSUSCHEM, 2015, 8 (11) :1885-1891
[7]   In Situ Generated Iron Oxide Nanocrystals as Efficient and Selective Catalysts for the Reduction of Nitroarenes using a Continuous Flow Method [J].
Cantillo, David ;
Baghbanzadeh, Mostafa ;
Kappe, C. Oliver .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (40) :10190-10193
[8]   Immobilized Ru Clusters in Nanosized Mesoporous Zirconium Silica for the Aqueous Hydrogenation of Furan Derivatives at Room Temperature [J].
Chen, Jiazhi ;
Lu, Fang ;
Zhang, Junjie ;
Yu, Weiqiang ;
Wang, Feng ;
Gao, Jin ;
Xu, Jie .
CHEMCATCHEM, 2013, 5 (10) :2822-2826
[9]   Interfacial Engineering of Nickel Boride/Metaborate and Its Effect on High Energy Density Asymmetric Supercapacitors [J].
Chen, Yuanzhen ;
Zhou, Tengfei ;
Li, Lei ;
Pang, Wei Kong ;
He, Xingmin ;
Liu, Yong-Ning ;
Guo, Zaiping .
ACS NANO, 2019, 13 (08) :9376-9385
[10]   Selective hydrogenation of citral over amorphous NiB and CoB nano-catalysts [J].
Chen, YZ ;
Liaw, BJ ;
Chiang, SJ .
APPLIED CATALYSIS A-GENERAL, 2005, 284 (1-2) :97-104