Research progress in biomass-based catalysts in the conversion of carbon dioxide into cyclic carbonates

被引：0

作者：

Liao, Xu ^{[1
]}

Wang, Wei ^{[1
]}

Huang, Wenting ^{[1
]}

Xiong, Wentao ^{[2
]}

Wang, Zeyu ^{[2
]}

Qin, Zuodong ^{[1
]}

Lin, Jinqing ^{[2
]}

机构：

[1] College of Chemistry and Bioengineering, Hunan University of Science and Engineering, Hunan, Yongzhou

[2] College of Materials Science and Engineering, Huaqiao University, Fujian, Xiamen

来源：

Huagong Jinzhan/Chemical Industry and Engineering Progress | 2025年 / 44卷 / 02期

关键词：

biomass material; carbon dioxide; catalyst; cyclic carbonate; multiphase reaction;

D O I：

10.16085/j.issn.1000-6613.2024-0265

中图分类号：

O6 [化学]; TQ03 [化学反应过程]; TQ02 [化工过程（物理过程及物理化学过程）];

学科分类号：

0703 ; 081701 ; 081704 ;

摘要：

The cyclo-addition of carbon dioxide (CO2) with epoxides is an effective and clean way to produce cyclic carbonates. As a kind of renewable resource, biomass-based catalysts have attracted wide attention because of their unique properties such as non-toxicity, low cost, non-pollution, and containing a large number of amino and hydroxyl groups. In this paper, the recent research progress in the synthesis of cyclic carbonates from CO2 and epoxides catalyzed by biomass-based materials such as lignin, cellulose, chitosan, and β-cyclodextrin is systematically reviewed. The synthesis methods, structural characteristics, and catalytic reaction mechanism of various biomass-based catalysts are discussed. The catalytic activity and reaction conditions of biomass-based catalysts for CO2 cycloaddition are summarized. However, CO2 cycloaddition with biomass-based catalysts is facing the problems of limited large-scale application, low catalytic efficiency, and difficulty in balancing CO2 capture and conversion. Finally, the application prospects were discussed to provide references and new ideas for the utilization of biomass materials and CO2 conversion. © 2025 Chemical Industry Press Co., Ltd.. All rights reserved.

引用

页码：834 / 846

页数：12

共 59 条

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