The main objective of this study is to assess the environmental life cycle of the materials, components, and elements of a mono-Si photovoltaic power plant towards their sustainable development. Currently, photovoltaic installations are considered to be environmentally friendly systems that produce "green" energy. During their exploitation, no pollutants are emitted into the environment. However, the processes of manufacturing and post-used management of their materials, components and elements are associated with both high demand for energy and matter, as well as with emissions of harmful substances into the atmosphere, water, and soil. For this reason, from the perspective of the entire life cycle, photovoltaic power plants may contribute to the deterioration of human health, the reduction in the quality of the environment, and the depletion of non-renewable fossil resources. Due to these potential threats, it was considered appropriate to conduct a Life Cycle Assessment of a real 2 MW photovoltaic power plant located in northern Poland, in terms of compliance with the main assumptions of sustainable development. The analysis was conducted using the Life Cycle Assessment (LCA) methodology (the ReCiPe 2016 model). Impacts on the environment was assessed in three areas: human health, ecosystem quality, and material resources. Two scenarios were adopted for the post-used management of materials, components, and elements: landfill disposal and recycling. Based on the conducted research, it was found that, among the assessed groups of photovoltaic power plant components (photovoltaic modules, supporting structure, inverter station, and electrical infra-structure), photovoltaic modules have the highest level of harmful impact on the environment (especially the manufacturing stage). The use of recycling processes at the end of their use would reduce their harmful impact over the entire life cycle of a photovoltaic power plant and better fit with the main principles of sustainable development.