Ruthenium-Catalyzed Isomerization/(Transfer) Hydrogenation of Allylic Alcohols

被引：0
作者：
Yang, Shuang [1 ]
Fang, Xinqiang [1 ]
机构：
[1] Univ Chinese Acad Sci, Fujian Inst Res Struct Matter, Ctr Excellence Mol Synth, State Key Lab Struct Chem, Fuzhou 350100, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2025年 / 57卷 / 16期
基金：
中国国家自然科学基金;
关键词：
allylic alcohol; hydrogenation; transfer hydrogenation; redox isomerization; ruthenium catalyst; ASYMMETRIC TRANSFER HYDROGENATION; ENANTIOSELECTIVE HYDROGENATION; MOLECULAR CATALYSTS; KINETIC RESOLUTION; CARBONYL-COMPOUNDS; CHIRAL LIGANDS; TANDEM; KETONES; REDUCTION; PRECURSOR;
D O I：
10.1055/a-2589-4376
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Allylic alcohols, renowned for their reactivity in epoxidation, dihydroxylation, allylic substitution, and isomerization, stand as pivotal intermediates in organic synthesis. While numerous reviews have delved into the above transformations of allylic alcohols, a significant void remains in the comprehensive discussion of their conversion into saturated alcohols under (transfer) hydrogenation conditions. This short review endeavors to fill that void by highlighting the tandem isomerization/(transfer) hydrogenation of allylic alcohols facilitated by ruthenium catalysts. We hope that this account will advance the understanding and application of allylic alcohols in (transfer) hydrogenation, fostering innovation and discovery in this critical area. 1 Introduction 2 Ruthenium-Catalyzed Conversion of Allylic Alcohols into Saturated Alcohols under Transfer Hydrogenation Conditions 3 Ruthenium-Catalyzed Conversion of Allylic Alcohols into Saturated Alcohols under Hydrogenation Conditions 4 Conclusion
引用
收藏
页码：2423 / 2433
页数：11
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