Buried Interface Modification with Nanoparticles for Efficient Perovskite Solar Cells with Improved Reproducibility

被引：0

作者：

Chen, Guanwen ^{[1
]}

Li, Ning ^{[1
]}

Li, Weijie ^{[1
]}

Liu, Xiaofan ^{[1
]}

Ning, Tao ^{[1
]}

Wang, Xia ^{[1
]}

Chen, Zhaolai ^{[2
]}

Cao, Bingqiang ^{[1
]}

机构：

[1] Univ Jinan, Sch Mat Sci & Engn, Jinan 250024, Peoples R China

[2] Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

来源：

ACS APPLIED ENERGY MATERIALS | 2025年 / 8卷 / 11期

关键词：

Perovskite solar cells; Buried interface modification; Nanoparticles; Efficient and stable devices; RECOMBINATION; BULK;

D O I：

10.1021/acsaem.5c01107

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The PCE of inverted PSCs is increasing due to advancements in SAMs and passivation techniques. However, the imperfections in the buried interface and uneven deposition of perovskite films impede the operational stability and reproducibility of the PSCs. Herein, Y2O3-NPs were employed as a functional interlayer to improve the wettability of SAMs-based hole transport substrate, resulting in the perovskite films with higher crystallinity, fewer defects and desired homogeneity, thus promoting hole extraction and suppressing nonradiative recombination in the buried interface of PSCs. The photovoltaic efficiency of the resulting devices increases from 23.0% to 24.9%, which is accompanied by exceptional reproducibility.

引用

页码：6897 / 6904

页数：8

共 30 条

[1] Understanding the Effect of Lead Iodide Excess on the Performance of Methylammonium Lead Iodide Perovskite Solar Cells [J].

Ahmad, Zeeshan ;

Scheidt, Rebecca A. ;

Hautzinger, Matthew P. ;

Zhu, Kai ;

Beard, Matthew C. ;

Galli, Giulia .

ACS ENERGY LETTERS, 2022, 7 (06) :1912-1919

[2] Monolithic perovskite/silicon tandem solar cell with >29% efficiency by enhanced hole extraction [J].

Al-Ashouri, Amran ;

Kohnen, Eike ;

Li, Bor ;

Magomedov, Artiom ;

Hempel, Hannes ;

Caprioglio, Pietro ;

Marquez, Jose A. ;

Vilches, Anna Belen Morales ;

Kasparavicius, Ernestas ;

Smith, Joel A. ;

Phung, Nga ;

Menzel, Dorothee ;

Grischek, Max ;

Kegelmann, Lukas ;

Skroblin, Dieter ;

Gollwitzer, Christian ;

Malinauskas, Tadas ;

Jost, Marko ;

Matic, Gasper ;

Rech, Bernd ;

Schlatmann, Rutger ;

Topic, Marko ;

Korte, Lars ;

Abate, Antonio ;

Stannowski, Bernd ;

Neher, Dieter ;

Stolterfoht, Martin ;

Unold, Thomas ;

Getautis, Vytautas ;

Albrecht, Steve .

SCIENCE, 2020, 370 (6522) :1300-+

[3] Small grains as recombination hot spots in perovskite solar cells [J].

An, Qingzhi ;

Paulus, Fabian ;

Becker-Koch, David ;

Cho, Changsoon ;

Sun, Qing ;

Weu, Andreas ;

Bitton, Sapir ;

Tessler, Nir ;

Vaynzof, Yana .

MATTER, 2021, 4 (05) :1683-1701

[4] Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells [J].

Bi, Cheng ;

Wang, Qi ;

Shao, Yuchuan ;

Yuan, Yongbo ;

Xiao, Zhengguo ;

Huang, Jinsong .

NATURE COMMUNICATIONS, 2015, 6

[5] Highly Efficient and Thickness Insensitive Inverted Triple-Cation Perovskite Solar Cells Fabricated by Gas Pumping Method [J].

Chen, Jianwu ;

Xu, Xuehui ;

Tang, Xiangyang ;

Jiang, Tingming ;

Chen, Zeng ;

Ye, Lei ;

Tian, Yue ;

Chen, Xu ;

Liu, Tianyu ;

Su, Yirong ;

Zhu, Haiming ;

Di, Dawei ;

Li, Linjun ;

Yang, Yang Michael .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2021, 12 (23) :5580-5586

[6] Reducing reflection of down-shifting solar cells through scattering by particles [J].

Diao, Han ;

Lou, Chaogang ;

Song, Guoxiang ;

Zhu, Ruiqi .

APPLIED PHYSICS LETTERS, 2024, 124 (13)

[7] Formation, location and beneficial role of PbI2 in lead halide perovskite solar cells [J].

Du, Tian ;

Burgess, Claire H. ;

Kim, Jinhyun ;

Zhang, Jiaqi ;

Durrant, James R. ;

McLachlan, Martyn A. .

SUSTAINABLE ENERGY & FUELS, 2017, 1 (01) :119-126

[8] Passivated rear contacts for high-efficiency n-type Si solar cells providing high interface passivation quality and excellent transport characteristics [J].

Feldmann, Frank ;

Bivour, Martin ;

Reichel, Christian ;

Hermle, Martin ;

Glunz, Stefan W. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2014, 120 :270-274

[9] Shape Control of Metal Halide Perovskite Single Crystals: From Bulk to Nanoscale [J].

Feng, Anbo ;

Jiang, Xiaomei ;

Zhang, Xiaoyu ;

Zheng, Xiaopeng ;

Zheng, Weitao ;

Mohammed, Omar F. ;

Chen, Zhaolai ;

Bakr, Osman M. .

CHEMISTRY OF MATERIALS, 2020, 32 (18) :7602-7617

[10] Improving interface quality for 1-cm2 all-perovskite tandem solar cells [J].

He, Rui ;

Wang, Wanhai ;

Yi, Zongjin ;

Lang, Felix ;

Chen, Cong ;

Luo, Jincheng ;

Zhu, Jingwei ;

Thiesbrummel, Jarla ;

Shah, Sahil ;

Wei, Kun ;

Luo, Yi ;

Wang, Changlei ;

Lai, Huagui ;

Huang, Hao ;

Zhou, Jie ;

Zou, Bingsuo ;

Yin, Xinxing ;

Ren, Shengqiang ;

Hao, Xia ;

Wu, Lili ;

Zhang, Jingquan ;

Zhang, Jinbao ;

Stolterfoht, Martin ;

Fu, Fan ;

Tang, Weihua ;

Zhao, Dewei .

NATURE, 2023, 618 (7963) :80-+

← 1 2 3 →