Investigation of the Frequency-Dependent Dielectric Properties of the As-Prepared LaNiO3/Co3O4 Nanocomposites

被引:0
作者
Mabrouki, Ala Eddin [4 ]
Messaoudi, Olfa [1 ]
Dhahri, Ahmed [2 ]
Azhary, Arwa [1 ]
Mansouri, Moufida [3 ]
Alfhaid, Latifah [1 ]
机构
[1] Univ Hail, Coll Sci, Phys Dept, ZA-2051 Hail, Saudi Arabia
[2] Shaqra Univ, Fac Sci & Humanities Addawadmi, Phys Dept, Shaqra 11911, Saudi Arabia
[3] Univ Sfax, Dept Phys, Sfax 3029, Tunisia
[4] Univ Sfax, Fac Sci Sfax, Lab Appl Phys, BP 1171, Sfax 3000, Tunisia
关键词
IMPEDANCE SPECTROSCOPY; ELECTRONIC-PROPERTIES; INSULATOR-TRANSITION; OPTICAL-PROPERTIES; RNIO3; R; TEMPERATURE; RELAXATION; CONDUCTIVITY; ND; LA;
D O I
10.1021/acsomega.4c11199
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This article presents a detailed study of the dielectric properties, AC conductivity, electric modulus, and impedance spectroscopy of the LaNiO3/Co3O4 as-prepared nanocomposite. The composite was prepared using the modified citrate gel autocombustion method. Transmission electron microscopy and atomic force microscopy images revealed nonuniform nanoparticles of varying shapes and sizes. Impedance analysis indicated a negative temperature coefficient of resistance and semiconducting behavior of the nanocomposite. The Nyquist plot displayed one semicircular curve. The AC conductivity was found to be dependent on both temperature and frequency, adhering to Jonscher's power law, with conductivity governed by a sudden hopping process. A high dissipation factor was observed, which decreased with frequency. A non-Debye relaxation type was defined for the nanocomposite.
引用
收藏
页码:22701 / 22710
页数:10
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